Pd-Catalyzed Enantio- and Regioselective Formation of Allylic Aryl Ethers

A general methodology for the synthesis of enantioenriched tertiary allylic aryl ethers through Pd-catalyzed decarbox- ylative reactions of vinyl cyclic carbonates and phenols is presented. Switching of the regioselectivity toward the formation of linear products by a judicious choice of the ligand...

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Detalles Bibliográficos
Autores: Xie, Jianing, Guo, Wusheng, Cai, Aijie, Escudero-Adán, Eduardo C., Kleij, Arjan W.
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2017
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/356270
Acceso en línea:http://hdl.handle.net/2072/356270
https://doi.org/10.1021/acs.orglett.7b03247
Access Level:acceso abierto
Palabra clave:54
Descripción
Sumario:A general methodology for the synthesis of enantioenriched tertiary allylic aryl ethers through Pd-catalyzed decarbox- ylative reactions of vinyl cyclic carbonates and phenols is presented. Switching of the regioselectivity toward the formation of linear products by a judicious choice of the ligand is also reported