A Bifunctional Metal/Acid Catalyst for One-Pot Multistep Synthesis of Pharmaceuticals

[EN] One inhibitor of the fatty acid transporter FATP4 was synthesized in a three steps one-pot process in the presence of a bifunctional metal/acid catalyst. This molecule which has potential interest for the treatment of the obesity in orlistat (Xenical(TM)) analogue-based therapies has a 3,4-dihy...

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Detalles Bibliográficos
Autores: López Prado, Mª Victoria, Sabater Picot, Mª José, Corma Canós, Avelino|||0000-0002-2232-3527
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/164994
Acceso en línea:https://riunet.upv.es/handle/10251/164994
Access Level:acceso abierto
Palabra clave:Pharmaceuticals
Dihydropyrimidinone
One-pot, synthesis
Bifunctional
Catalyst
QUIMICA ORGANICA
Descripción
Sumario:[EN] One inhibitor of the fatty acid transporter FATP4 was synthesized in a three steps one-pot process in the presence of a bifunctional metal/acid catalyst. This molecule which has potential interest for the treatment of the obesity in orlistat (Xenical(TM)) analogue-based therapies has a 3,4-dihydropyrimidin-2(1H)-one (DHPM) scaffold and was obtained by means of a three one-pot process through successive oxidation, cyclocondensation and transesterification reactions. The one-pot strategy was extended to the synthesis of a series of related ester DHPM derivatives.