How to Make an Efficient and Robust Molecular Catalyst for Water Oxidation

<p> Energy has been a central subject for human development from <em>Homo erectus</em> to date. The massive use of fossil fuels during the last 50 years has generated a large CO2 concentration in the atmosphere that has led to the so-called global warming. It is very urgent to come...

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Autores: Garrido-Barros, Pablo, Gimbert-Suriñach, Carolina, Matheu, Roc, Sala, Xavier, Llobet, Antoni
Tipo de recurso: artículo
Fecha de publicación:2017
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/305770
Acceso en línea:http://hdl.handle.net/2072/305770
https://doi.org/10.1039/C7CS00248C
Access Level:acceso abierto
Palabra clave:Transition metal complexe s
Water oxidation catalysis
Water splitting
New energy conversion schemes
Degradation pathways
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spelling How to Make an Efficient and Robust Molecular Catalyst for Water OxidationGarrido-Barros, PabloGimbert-Suriñach, CarolinaMatheu, RocSala, XavierLlobet, AntoniTransition metal complexe sWater oxidation catalysisWater splittingNew energy conversion schemesDegradation pathways<p> Energy has been a central subject for human development from <em>Homo erectus</em> to date. The massive use of fossil fuels during the last 50 years has generated a large CO2 concentration in the atmosphere that has led to the so-called global warming. It is very urgent to come up with C-neutral energy schemes to be able to preserve Planet Earth for future generations to come and still preserve our modern societies&#39; life style. One of the potential solutions is water splitting with sunlight (<em>h&nu;</em>-WS) that is also associated with &ldquo;artificial photosynthesis&rdquo;, since its working mode consists of light capture followed by water oxidation and proton reduction processes. The hydrogen fuel generated in this way is named as &ldquo;solar fuel&rdquo;. For this set of reactions, the catalytic oxidation of water to dioxygen is one of the crucial processes that need to be understood and mastered in order to build up potential devices based on <em>h&nu;</em>-WS. This tutorial describes the different important aspects that need to be considered to come up with efficient and oxidatively robust molecular water oxidation catalysts (Mol-WOCs). It is based on our own previous work and completed with essential contributions from other active groups in the field. We mainly aim at describing how the ligands can influence the properties of the Mol-WOCs and showing a few key examples that overall provide a complete view of today&#39;s understanding in this field.</p>RSC2017info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/2072/305770https://doi.org/10.1039/C7CS00248CRECERCAT (Dipòsit de la Recerca de Catalunya)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésMINECO with FEDER FundsProyectos I+D+i - Retos 2016Severo Ochoa Excellence Accreditation 2014-2018MC4WSChem. Soc. RevCTQ2016-80058-RSEV2013-0319 I I CTQ2016-81923-REDC© The Royal Society of Chemistry 2017info:eu-repo/semantics/openAccessoai:recercat.cat:2072/3057702026-05-29T05:05:01Z
dc.title.none.fl_str_mv How to Make an Efficient and Robust Molecular Catalyst for Water Oxidation
title How to Make an Efficient and Robust Molecular Catalyst for Water Oxidation
spellingShingle How to Make an Efficient and Robust Molecular Catalyst for Water Oxidation
Garrido-Barros, Pablo
Transition metal complexe s
Water oxidation catalysis
Water splitting
New energy conversion schemes
Degradation pathways
title_short How to Make an Efficient and Robust Molecular Catalyst for Water Oxidation
title_full How to Make an Efficient and Robust Molecular Catalyst for Water Oxidation
title_fullStr How to Make an Efficient and Robust Molecular Catalyst for Water Oxidation
title_full_unstemmed How to Make an Efficient and Robust Molecular Catalyst for Water Oxidation
title_sort How to Make an Efficient and Robust Molecular Catalyst for Water Oxidation
dc.creator.none.fl_str_mv Garrido-Barros, Pablo
Gimbert-Suriñach, Carolina
Matheu, Roc
Sala, Xavier
Llobet, Antoni
author Garrido-Barros, Pablo
author_facet Garrido-Barros, Pablo
Gimbert-Suriñach, Carolina
Matheu, Roc
Sala, Xavier
Llobet, Antoni
author_role author
author2 Gimbert-Suriñach, Carolina
Matheu, Roc
Sala, Xavier
Llobet, Antoni
author2_role author
author
author
author
dc.subject.none.fl_str_mv Transition metal complexe s
Water oxidation catalysis
Water splitting
New energy conversion schemes
Degradation pathways
topic Transition metal complexe s
Water oxidation catalysis
Water splitting
New energy conversion schemes
Degradation pathways
description <p> Energy has been a central subject for human development from <em>Homo erectus</em> to date. The massive use of fossil fuels during the last 50 years has generated a large CO2 concentration in the atmosphere that has led to the so-called global warming. It is very urgent to come up with C-neutral energy schemes to be able to preserve Planet Earth for future generations to come and still preserve our modern societies&#39; life style. One of the potential solutions is water splitting with sunlight (<em>h&nu;</em>-WS) that is also associated with &ldquo;artificial photosynthesis&rdquo;, since its working mode consists of light capture followed by water oxidation and proton reduction processes. The hydrogen fuel generated in this way is named as &ldquo;solar fuel&rdquo;. For this set of reactions, the catalytic oxidation of water to dioxygen is one of the crucial processes that need to be understood and mastered in order to build up potential devices based on <em>h&nu;</em>-WS. This tutorial describes the different important aspects that need to be considered to come up with efficient and oxidatively robust molecular water oxidation catalysts (Mol-WOCs). It is based on our own previous work and completed with essential contributions from other active groups in the field. We mainly aim at describing how the ligands can influence the properties of the Mol-WOCs and showing a few key examples that overall provide a complete view of today&#39;s understanding in this field.</p>
publishDate 2017
dc.date.none.fl_str_mv 2017
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/2072/305770
https://doi.org/10.1039/C7CS00248C
url http://hdl.handle.net/2072/305770
https://doi.org/10.1039/C7CS00248C
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv MINECO with FEDER Funds
Proyectos I+D+i - Retos 2016
Severo Ochoa Excellence Accreditation 2014-2018
MC4WS
Chem. Soc. Rev
CTQ2016-80058-R
SEV2013-0319 I I CTQ2016-81923-REDC
dc.rights.none.fl_str_mv © The Royal Society of Chemistry 2017
info:eu-repo/semantics/openAccess
rights_invalid_str_mv © The Royal Society of Chemistry 2017
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv RSC
publisher.none.fl_str_mv RSC
dc.source.none.fl_str_mv RECERCAT (Dipòsit de la Recerca de Catalunya)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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