Copper-catalysed radical reactions of alkenes, alkynes and cyclopropanes with N–F reagents
The mild generation of nitrogen-centred radicals from N–F reagents has become a convenient synthetic tool. This methodology provides access to the aminative difunctionalisation of alkenes and alkynes and the radical ring-opening of cyclopropanes, among other similar transformations. This review arti...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2020 |
| País: | España |
| Institución: | Universidad de Huelva (UHU) |
| Repositorio: | Arias Montano. Repositorio Institucional de la Universidad de Huelva |
| Idioma: | inglés |
| OAI Identifier: | oai:ariasmontano.uhu.es:10272/19621 |
| Acceso en línea: | http://hdl.handle.net/10272/19621 |
| Access Level: | acceso abierto |
| Palabra clave: | Copper Copper-catalysed Radical reactions Alkenes Alkynes Cyclopropanes N–F reagents 23 Química |
| Sumario: | The mild generation of nitrogen-centred radicals from N–F reagents has become a convenient synthetic tool. This methodology provides access to the aminative difunctionalisation of alkenes and alkynes and the radical ring-opening of cyclopropanes, among other similar transformations. This review article aims to provide an overview of recent developments of such processes involving radical reactions and N–F reagents using copper-based catalysts. |
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