BaCe0.6Zr0.3Y0.1O3-α electrochemical hydrogen sensor for fusion applications

Potentiometric sensors are broadening their application scope because they are affordable and scalable devices capable of being used in-field and online. In that frame, the use of proton-conducting solid-state electrolytes in these sensors architecture offers the possibility to operate at high tempe...

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Detalles Bibliográficos
Autores: Hinojo, Antonio, Lujan, Enric, Nel-lo, Marc, Colominas, Sergi, Abella, Jordi
Tipo de recurso: artículo
Fecha de publicación:2023
País:España
Institución:Universitat Ramon Llull (URL)
Repositorio:DAU Arxiu Digital de la Universitat Ramon Llull
OAI Identifier:oai:dau.url.edu:20.500.14342/5310
Acceso en línea:http://hdl.handle.net/20.500.14342/5310
https://doi.org/10.1016/j.fusengdes.2023.113452
Access Level:acceso abierto
Palabra clave:BCZY
High-temperature
Potentiometric
Perovskite
Temperatures altes
Potenciometria
Perovskita
544
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repository_id_str
spelling BaCe0.6Zr0.3Y0.1O3-α electrochemical hydrogen sensor for fusion applicationsHinojo, AntonioLujan, EnricNel-lo, MarcColominas, SergiAbella, JordiBCZYHigh-temperaturePotentiometricPerovskiteTemperatures altesPotenciometriaPerovskita544Potentiometric sensors are broadening their application scope because they are affordable and scalable devices capable of being used in-field and online. In that frame, the use of proton-conducting solid-state electrolytes in these sensors architecture offers the possibility to operate at high temperatures, with high physical and chemical stabilities. A potential application for this kind of sensor is tritium monitoring in future fusion reactors. The first steps toward the development of this analytical tool will be devices capable of measuring hydrogen in high temperature applications In the present work, a potentiometric sensor based on BaCe0.6Zr0.3Y0.1O3-α (BCZY) solid-state proton-conductor was tested for hydrogen monitoring at 325 °C, 350 °C and 375 °C. BCZY was synthesized by the solid-state method and characterized using XRD. The sensor's linear range, accuracy and limit of detection were evaluated at the selected temperatures (325 °C, 350 °C and 375 °C). Moreover, sensors presented a very short response and recovery times (<100 s).info:eu-repo/semantics/acceptedVersionElsevierUniversitat Ramon Llull. IQS202520252023info:eu-repo/semantics/articlep.6application/pdfhttp://hdl.handle.net/20.500.14342/5310https://doi.org/10.1016/j.fusengdes.2023.113452reponame:DAU Arxiu Digital de la Universitat Ramon Llullinstname:Universitat Ramon Llull (URL)InglésFusion Engineering and Design, 2023, 188info:eu-repo/grantAgreement/ERDF/ERDF Operational Program of Catalonia 2014-2020/001-P-001722© ElsevierAttribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:dau.url.edu:20.500.14342/53102026-06-21T06:40:37Z
dc.title.none.fl_str_mv BaCe0.6Zr0.3Y0.1O3-α electrochemical hydrogen sensor for fusion applications
title BaCe0.6Zr0.3Y0.1O3-α electrochemical hydrogen sensor for fusion applications
spellingShingle BaCe0.6Zr0.3Y0.1O3-α electrochemical hydrogen sensor for fusion applications
Hinojo, Antonio
BCZY
High-temperature
Potentiometric
Perovskite
Temperatures altes
Potenciometria
Perovskita
544
title_short BaCe0.6Zr0.3Y0.1O3-α electrochemical hydrogen sensor for fusion applications
title_full BaCe0.6Zr0.3Y0.1O3-α electrochemical hydrogen sensor for fusion applications
title_fullStr BaCe0.6Zr0.3Y0.1O3-α electrochemical hydrogen sensor for fusion applications
title_full_unstemmed BaCe0.6Zr0.3Y0.1O3-α electrochemical hydrogen sensor for fusion applications
title_sort BaCe0.6Zr0.3Y0.1O3-α electrochemical hydrogen sensor for fusion applications
dc.creator.none.fl_str_mv Hinojo, Antonio
Lujan, Enric
Nel-lo, Marc
Colominas, Sergi
Abella, Jordi
author Hinojo, Antonio
author_facet Hinojo, Antonio
Lujan, Enric
Nel-lo, Marc
Colominas, Sergi
Abella, Jordi
author_role author
author2 Lujan, Enric
Nel-lo, Marc
Colominas, Sergi
Abella, Jordi
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Universitat Ramon Llull. IQS
dc.subject.none.fl_str_mv BCZY
High-temperature
Potentiometric
Perovskite
Temperatures altes
Potenciometria
Perovskita
544
topic BCZY
High-temperature
Potentiometric
Perovskite
Temperatures altes
Potenciometria
Perovskita
544
description Potentiometric sensors are broadening their application scope because they are affordable and scalable devices capable of being used in-field and online. In that frame, the use of proton-conducting solid-state electrolytes in these sensors architecture offers the possibility to operate at high temperatures, with high physical and chemical stabilities. A potential application for this kind of sensor is tritium monitoring in future fusion reactors. The first steps toward the development of this analytical tool will be devices capable of measuring hydrogen in high temperature applications In the present work, a potentiometric sensor based on BaCe0.6Zr0.3Y0.1O3-α (BCZY) solid-state proton-conductor was tested for hydrogen monitoring at 325 °C, 350 °C and 375 °C. BCZY was synthesized by the solid-state method and characterized using XRD. The sensor's linear range, accuracy and limit of detection were evaluated at the selected temperatures (325 °C, 350 °C and 375 °C). Moreover, sensors presented a very short response and recovery times (<100 s).
publishDate 2023
dc.date.none.fl_str_mv 2023
2025
2025
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/20.500.14342/5310
https://doi.org/10.1016/j.fusengdes.2023.113452
url http://hdl.handle.net/20.500.14342/5310
https://doi.org/10.1016/j.fusengdes.2023.113452
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Fusion Engineering and Design, 2023, 188
info:eu-repo/grantAgreement/ERDF/ERDF Operational Program of Catalonia 2014-2020/001-P-001722
dc.rights.none.fl_str_mv © Elsevier
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv © Elsevier
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv p.6
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DAU Arxiu Digital de la Universitat Ramon Llull
instname:Universitat Ramon Llull (URL)
instname_str Universitat Ramon Llull (URL)
reponame_str DAU Arxiu Digital de la Universitat Ramon Llull
collection DAU Arxiu Digital de la Universitat Ramon Llull
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,811543

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