Influence of Hot Compaction on Microstructure and Magnetic Properties of Mechanically Alloyed Fe(Co)-based Amorphous Compositions

Amorphous Fe75Nb10B15 and (Fe70Co30)75Nb10B15 alloys were prepared by mechanical alloying from the elemental constituents and hot compacted at different temperatures within the supercooled liquid region. After compaction, the microstructure studied by X-ray diffraction shows an increase in the cryst...

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Detalhes bibliográficos
Autores: Ipus Bados, Jhon Jairo, Borrego Moro, Josefa María, Blázquez Gámez, Javier Sebastián, Stoica, M., Franco García, Victorino, Conde Amiano, Alejandro
Formato: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2015
País:España
Recursos:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/147214
Acesso em linha:https://hdl.handle.net/11441/147214
https://doi.org/10.1016/j.jallcom.2015.09.074
Access Level:acceso abierto
Palavra-chave:Amorphous and nanocrystalline alloys
Hot compaction
Magnetocaloric effect
Mechanical alloying
Descrição
Resumo:Amorphous Fe75Nb10B15 and (Fe70Co30)75Nb10B15 alloys were prepared by mechanical alloying from the elemental constituents and hot compacted at different temperatures within the supercooled liquid region. After compaction, the microstructure studied by X-ray diffraction shows an increase in the crystalline fraction for both compositions. Magnetic properties and magnetic entropy change of compacted samples of the Co-free alloy were enhanced with respect to the powder sample, meanwhile, a deterioration in these properties was observed for the Co containing alloy after compaction. Both changes could be ascribed to an enrichment in boron in the amorphous phase.