Generalized kinetic master plots for the thermal degradation of polymers following a random scission mechanism
In this paper, the f(¿) conversion functions for random scission mechanisms have been proposed to allow for the construction of generalized master plots suitable for these kinds of mechanisms. The master plots have been validated by their application to simulated data and to the thermal degradation...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2010 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/97253 |
| Acceso en línea: | http://hdl.handle.net/10261/97253 |
| Access Level: | acceso abierto |
| Palabra clave: | Random scission Polymer degradation Mechanisms Master plots Kinetics |
| Sumario: | In this paper, the f(¿) conversion functions for random scission mechanisms have been proposed to allow for the construction of generalized master plots suitable for these kinds of mechanisms. The master plots have been validated by their application to simulated data and to the thermal degradation of poly(butylene terephthalate), polyethylene, and poly(tetrafluoroethylene). © 2010 American Chemical Society. |
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