Generalized master plots as a straightforward approach for determining the kinetic model: The case of cellulose pyrolysis
The thermal degradation of cellulose is a complex reaction and, despite the large amount of work by many investigators during the last decades, the actual understanding of the thermal decomposition kinetics is still very limited. Thus, while several mechanisms have been proposed to describe the proc...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión enviada para evaluación y publicación |
| Fecha de publicación: | 2013 |
| País: | España |
| Institución: | Universidad de Sevilla (US) |
| Repositorio: | idUS. Depósito de Investigación de la Universidad de Sevilla |
| OAI Identifier: | oai:idus.us.es:11441/70596 |
| Acceso en línea: | https://hdl.handle.net/11441/70596 https://doi.org/10.1016/j.tca.2012.11.003 |
| Access Level: | acceso abierto |
| Palabra clave: | Kinetics Cellulose Thermal degradation Random scission Master plots Pyrolisis |
| Sumario: | The thermal degradation of cellulose is a complex reaction and, despite the large amount of work by many investigators during the last decades, the actual understanding of the thermal decomposition kinetics is still very limited. Thus, while several mechanisms have been proposed to describe the process, the real model has not yet been clearly identified. In this paper, a set of experimental curves recorded under different heating schedules, i.e., linear heating rate, isothermal and constant rate thermal analysis (CRTA), has been analyzed using isoconversional and master plots methodology to discriminate the kinetic model followed by the reaction. |
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