C*-BODIPYs: Exploring a New Strategy to Transfer Chirality towards BODIPY Chiroptics

C*-BODIPYs, that is, boron dipyrromethenes (BODIPYs) which have chiral carbons attached directly to the boron center, are introduced for the first time. These novel chiral BODIPYs mean a new strategy for the chiral perturbation of the inherently achiral BODIPY chromophore that is directed to enable...

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Detalhes bibliográficos
Autores: Jiménez González, Josué, Sánchez Camacho, Juan, Moreno Jiménez, Florencio, Rodríguez Agarrabeitia, Antonia, Arbeloa, Teresa, Cabreros, Trevor A., Muller, Gilles, Bañuelos, Jorge, Maroto, Beatriz Lora, Moya Cerero, Santiago de la
Formato: artículo
Fecha de publicación:2020
País:España
Recursos:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/8285
Acesso em linha:https://hdl.handle.net/20.500.14352/8285
Access Level:acceso abierto
Palavra-chave:BODIPYs
circular dichroism
circularly polarized luminescence
CPL-SOMs
Química orgánica (Química)
2306 Química Orgánica
Descrição
Resumo:C*-BODIPYs, that is, boron dipyrromethenes (BODIPYs) which have chiral carbons attached directly to the boron center, are introduced for the first time. These novel chiral BODIPYs mean a new strategy for the chiral perturbation of the inherently achiral BODIPY chromophore that is directed to enable chiroptical properties. Their preparation is very simple and only implies the complexation of a dipyrrin with an enantiopure dialkylborane having boron bonded to chiral carbons.

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