Exploring N-BODIPYs as Privileged Scaffolds to Build Off/On Fluorescent Sensors by PET

A new N-boron dipyrromethene (N-BODIPY) substituted with a crown ether moiety has been synthesized by reaction of an F-BODIPY with a crown-ether-substituted bis(sulfonamide). The workability of this N-BODIPY as an off/on sensor for cations by modulation of a photoinduced electron transfer (PET) is e...

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Detalles Bibliográficos
Autores: Ray Leiva, César, Schad, Christopher, Avellanal-Zaballa, Edurne, Moreno Jiménez, Florencio, Bañuelos, Jorge, Maroto, Beatriz Lora, Moya Cerero, Santiago de la
Tipo de recurso: artículo
Fecha de publicación:2019
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/8286
Acceso en línea:https://hdl.handle.net/20.500.14352/8286
Access Level:acceso abierto
Palabra clave:BODIPYs
N-BODIPYs
fluorescent sensors
off/on sensors
photoinduced electron transfer
Química orgánica (Química)
2306 Química Orgánica
Descripción
Sumario:A new N-boron dipyrromethene (N-BODIPY) substituted with a crown ether moiety has been synthesized by reaction of an F-BODIPY with a crown-ether-substituted bis(sulfonamide). The workability of this N-BODIPY as an off/on sensor for cations by modulation of a photoinduced electron transfer (PET) is explored. The new N-BODIPY demonstrates the possibilities of functionalization of these still unexplored but promising dyes.

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