Synthesis of mono‑n‑methyl aromatic amines from nitroso compounds and methylboronic acid

The selective synthesis of mono-N-methyl aromatic amines was achieved by the reaction of aromatic nitroso compounds with methylboronic acid promoted by triethylphosphite under transition metal-free conditions. The target compounds are constructed efficiently without overmethylation, under environmen...

Descripción completa

Detalles Bibliográficos
Autores: García Csaky, Aurelio, Roscales García, Silvia
Tipo de recurso: artículo
Fecha de publicación:2019
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/113025
Acceso en línea:https://hdl.handle.net/20.500.14352/113025
Access Level:acceso abierto
Palabra clave:547
Boronic acids
Amination reaction
Nitroso compounds
Química orgánica (Química)
2306 Química Orgánica
id ES_d5aaba88d1230a8b9e44ca567f48becd
oai_identifier_str oai:docta.ucm.es:20.500.14352/113025
network_acronym_str ES
network_name_str España
repository_id_str
spelling Synthesis of mono‑n‑methyl aromatic amines from nitroso compounds and methylboronic acidSíntesis de aminas aromáticas mono-N-metiladas a partir de nitrosocompuestos y ácidos metilborónicosGarcía Csaky, AurelioRoscales García, Silvia547Boronic acidsAmination reactionNitroso compoundsQuímica orgánica (Química)2306 Química OrgánicaThe selective synthesis of mono-N-methyl aromatic amines was achieved by the reaction of aromatic nitroso compounds with methylboronic acid promoted by triethylphosphite under transition metal-free conditions. The target compounds are constructed efficiently without overmethylation, under environmentally benign reaction conditions that do not require bases or reductants and therefore are of interest in pharmaceutical, agricultural, and chemical industries.American Chemical SocietyUniversidad Complutense de Madrid20192019-08-0120192019-08-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/20.500.14352/113025reponame:Docta Complutenseinstname:Universidad Complutense de Madrid (UCM)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:docta.ucm.es:20.500.14352/1130252026-06-02T12:44:21Z
dc.title.none.fl_str_mv Synthesis of mono‑n‑methyl aromatic amines from nitroso compounds and methylboronic acid
Síntesis de aminas aromáticas mono-N-metiladas a partir de nitrosocompuestos y ácidos metilborónicos
title Synthesis of mono‑n‑methyl aromatic amines from nitroso compounds and methylboronic acid
spellingShingle Synthesis of mono‑n‑methyl aromatic amines from nitroso compounds and methylboronic acid
García Csaky, Aurelio
547
Boronic acids
Amination reaction
Nitroso compounds
Química orgánica (Química)
2306 Química Orgánica
title_short Synthesis of mono‑n‑methyl aromatic amines from nitroso compounds and methylboronic acid
title_full Synthesis of mono‑n‑methyl aromatic amines from nitroso compounds and methylboronic acid
title_fullStr Synthesis of mono‑n‑methyl aromatic amines from nitroso compounds and methylboronic acid
title_full_unstemmed Synthesis of mono‑n‑methyl aromatic amines from nitroso compounds and methylboronic acid
title_sort Synthesis of mono‑n‑methyl aromatic amines from nitroso compounds and methylboronic acid
dc.creator.none.fl_str_mv García Csaky, Aurelio
Roscales García, Silvia
author García Csaky, Aurelio
author_facet García Csaky, Aurelio
Roscales García, Silvia
author_role author
author2 Roscales García, Silvia
author2_role author
dc.contributor.none.fl_str_mv Universidad Complutense de Madrid
dc.subject.none.fl_str_mv 547
Boronic acids
Amination reaction
Nitroso compounds
Química orgánica (Química)
2306 Química Orgánica
topic 547
Boronic acids
Amination reaction
Nitroso compounds
Química orgánica (Química)
2306 Química Orgánica
description The selective synthesis of mono-N-methyl aromatic amines was achieved by the reaction of aromatic nitroso compounds with methylboronic acid promoted by triethylphosphite under transition metal-free conditions. The target compounds are constructed efficiently without overmethylation, under environmentally benign reaction conditions that do not require bases or reductants and therefore are of interest in pharmaceutical, agricultural, and chemical industries.
publishDate 2019
dc.date.none.fl_str_mv 2019
2019-08-01
2019
2019-08-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/20.500.14352/113025
url https://hdl.handle.net/20.500.14352/113025
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:Docta Complutense
instname:Universidad Complutense de Madrid (UCM)
instname_str Universidad Complutense de Madrid (UCM)
reponame_str Docta Complutense
collection Docta Complutense
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869420745536307200
score 15,811543

Similares en LA Referencia