Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic Properties

The Fe65Co35 alloy is a well-known Fe-based soft ferromagnetic alloy with excellent soft magnetic properties, which make it a strong candidate to be used in technological applications. In the present work, synthesizing nanoscrystalline Fe65Co35 alloy by mechanical alloying is focused on, adding cycl...

ver descrição completa

Detalhes bibliográficos
Autores: Daza Collier, Jason, Curbelo-Cano, Zaida, Montero, Cristina M., Ben Mbarek, Wael, Escoda i Acero, Ma. Lluïsa, Saurina Canals, Joan, Palmero, Ester M., Bollero, Alberto, Bruna, Pere, Suñol Martínez, Joan Josep
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:España
Recursos:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/26862
Acesso em linha:http://hdl.handle.net/10256/26862
Access Level:acceso abierto
Palavra-chave:Aliatges
Alloys
Aliatge mecànic
Mechanical alloying
Ferro -- Aliatges
Iron alloys
Ferromagnetisme
Ferromagnetism
id ES_d59017e02b93e00bb8a88d740871a068
oai_identifier_str oai:recercat.cat:10256/26862
network_acronym_str ES
network_name_str España
repository_id_str
spelling Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic PropertiesDaza Collier, JasonCurbelo-Cano, ZaidaMontero, Cristina M.Ben Mbarek, WaelEscoda i Acero, Ma. LluïsaSaurina Canals, JoanPalmero, Ester M.Bollero, AlbertoBruna, PereSuñol Martínez, Joan JosepAliatgesAlloysAliatge mecànicMechanical alloyingFerro -- AliatgesIron alloysFerromagnetismeFerromagnetismThe Fe65Co35 alloy is a well-known Fe-based soft ferromagnetic alloy with excellent soft magnetic properties, which make it a strong candidate to be used in technological applications. In the present work, synthesizing nanoscrystalline Fe65Co35 alloy by mechanical alloying is focused on, adding cyclohexane (C6H12) acting as a process control agent (PCA). PCAs are effective in favoring nanostructured alloys with uniform grain size. The production of this type of alloy is a promising approach to tune the magnetic hardness in Fe65Co35. Structural, thermal, morphological, and magnetic properties have been studied after milling for 10, 25, and 50 h with and without the PCA. In the structural analysis, it is shown that the cubic α-Fe(Co) phase is the predominant phase in all samples. The use of the PCA favors its nanocrystallinity; however, it slows Co diffusion into the Fe matrix. Thermal analysis detects an endothermic process between 525 and 575 °C in the samples milled with C6H12 only. This is associated with the transition of the residual Fe3Co superlattice, to the stable α-Fe(Co). The effect of the residual Fe3Co at room temperature on the magnetic properties is twofold, by decreasing the saturation magnetization of Fe65Co35 but increasing both remanent magnetization and coercivityEls autors agraeixen el suport del MICINN-AEI a través del projecte NEXUS (PID2020-115215RB-C21 i PID2020-115215RB-C22). L'EMP agraeix el suport de l'AEI a través del programa Juan de la Cierva–Incorporación (beca IJC2020-043011-I/MCIN/AEI/10.13039/501100011033) i de la UE per NextGenerationEU/PRTR. L'IMDEA agraeix el suport del MICINN-AEI a través del Programa "Severo Ochoa" per a Centres d'Excel·lència en R+D (CEX2020-001039-S), i de la Comunitat de Madrid a través del projecte NANOMAGCOST (S2018/NMT-4321)Open Access funding provided thanks to the CRUE-CSIC agreement with WileyWiley2025info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionpeer-reviewedapplication/pdfhttp://hdl.handle.net/10256/26862http://hdl.handle.net/10256/26862Advanced Engineering Materials, 2025, vol. 27. núm. 6, p. 2402317Articles publicats (D-F)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)Inglésinfo:eu-repo/semantics/altIdentifier/doi/10.1002/adem.202402317info:eu-repo/semantics/altIdentifier/issn/1438-1656info:eu-repo/semantics/altIdentifier/eissn/1527-2648Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:recercat.cat:10256/268622026-05-29T05:05:01Z
dc.title.none.fl_str_mv Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic Properties
title Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic Properties
spellingShingle Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic Properties
Daza Collier, Jason
Aliatges
Alloys
Aliatge mecànic
Mechanical alloying
Ferro -- Aliatges
Iron alloys
Ferromagnetisme
Ferromagnetism
title_short Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic Properties
title_full Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic Properties
title_fullStr Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic Properties
title_full_unstemmed Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic Properties
title_sort Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic Properties
dc.creator.none.fl_str_mv Daza Collier, Jason
Curbelo-Cano, Zaida
Montero, Cristina M.
Ben Mbarek, Wael
Escoda i Acero, Ma. Lluïsa
Saurina Canals, Joan
Palmero, Ester M.
Bollero, Alberto
Bruna, Pere
Suñol Martínez, Joan Josep
author Daza Collier, Jason
author_facet Daza Collier, Jason
Curbelo-Cano, Zaida
Montero, Cristina M.
Ben Mbarek, Wael
Escoda i Acero, Ma. Lluïsa
Saurina Canals, Joan
Palmero, Ester M.
Bollero, Alberto
Bruna, Pere
Suñol Martínez, Joan Josep
author_role author
author2 Curbelo-Cano, Zaida
Montero, Cristina M.
Ben Mbarek, Wael
Escoda i Acero, Ma. Lluïsa
Saurina Canals, Joan
Palmero, Ester M.
Bollero, Alberto
Bruna, Pere
Suñol Martínez, Joan Josep
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Aliatges
Alloys
Aliatge mecànic
Mechanical alloying
Ferro -- Aliatges
Iron alloys
Ferromagnetisme
Ferromagnetism
topic Aliatges
Alloys
Aliatge mecànic
Mechanical alloying
Ferro -- Aliatges
Iron alloys
Ferromagnetisme
Ferromagnetism
description The Fe65Co35 alloy is a well-known Fe-based soft ferromagnetic alloy with excellent soft magnetic properties, which make it a strong candidate to be used in technological applications. In the present work, synthesizing nanoscrystalline Fe65Co35 alloy by mechanical alloying is focused on, adding cyclohexane (C6H12) acting as a process control agent (PCA). PCAs are effective in favoring nanostructured alloys with uniform grain size. The production of this type of alloy is a promising approach to tune the magnetic hardness in Fe65Co35. Structural, thermal, morphological, and magnetic properties have been studied after milling for 10, 25, and 50 h with and without the PCA. In the structural analysis, it is shown that the cubic α-Fe(Co) phase is the predominant phase in all samples. The use of the PCA favors its nanocrystallinity; however, it slows Co diffusion into the Fe matrix. Thermal analysis detects an endothermic process between 525 and 575 °C in the samples milled with C6H12 only. This is associated with the transition of the residual Fe3Co superlattice, to the stable α-Fe(Co). The effect of the residual Fe3Co at room temperature on the magnetic properties is twofold, by decreasing the saturation magnetization of Fe65Co35 but increasing both remanent magnetization and coercivity
publishDate 2025
dc.date.none.fl_str_mv 2025
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
peer-reviewed
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10256/26862
http://hdl.handle.net/10256/26862
url http://hdl.handle.net/10256/26862
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/adem.202402317
info:eu-repo/semantics/altIdentifier/issn/1438-1656
info:eu-repo/semantics/altIdentifier/eissn/1527-2648
dc.rights.none.fl_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv Advanced Engineering Materials, 2025, vol. 27. núm. 6, p. 2402317
Articles publicats (D-F)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869420713311469568
score 15.198674