Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic Properties
The Fe65Co35 alloy is a well-known Fe-based soft ferromagnetic alloy with excellent soft magnetic properties, which make it a strong candidate to be used in technological applications. In the present work, synthesizing nanoscrystalline Fe65Co35 alloy by mechanical alloying is focused on, adding cycl...
| Autores: | , , , , , , , , , |
|---|---|
| Formato: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2025 |
| País: | España |
| Recursos: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:10256/26862 |
| Acesso em linha: | http://hdl.handle.net/10256/26862 |
| Access Level: | acceso abierto |
| Palavra-chave: | Aliatges Alloys Aliatge mecànic Mechanical alloying Ferro -- Aliatges Iron alloys Ferromagnetisme Ferromagnetism |
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Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic PropertiesDaza Collier, JasonCurbelo-Cano, ZaidaMontero, Cristina M.Ben Mbarek, WaelEscoda i Acero, Ma. LluïsaSaurina Canals, JoanPalmero, Ester M.Bollero, AlbertoBruna, PereSuñol Martínez, Joan JosepAliatgesAlloysAliatge mecànicMechanical alloyingFerro -- AliatgesIron alloysFerromagnetismeFerromagnetismThe Fe65Co35 alloy is a well-known Fe-based soft ferromagnetic alloy with excellent soft magnetic properties, which make it a strong candidate to be used in technological applications. In the present work, synthesizing nanoscrystalline Fe65Co35 alloy by mechanical alloying is focused on, adding cyclohexane (C6H12) acting as a process control agent (PCA). PCAs are effective in favoring nanostructured alloys with uniform grain size. The production of this type of alloy is a promising approach to tune the magnetic hardness in Fe65Co35. Structural, thermal, morphological, and magnetic properties have been studied after milling for 10, 25, and 50 h with and without the PCA. In the structural analysis, it is shown that the cubic α-Fe(Co) phase is the predominant phase in all samples. The use of the PCA favors its nanocrystallinity; however, it slows Co diffusion into the Fe matrix. Thermal analysis detects an endothermic process between 525 and 575 °C in the samples milled with C6H12 only. This is associated with the transition of the residual Fe3Co superlattice, to the stable α-Fe(Co). The effect of the residual Fe3Co at room temperature on the magnetic properties is twofold, by decreasing the saturation magnetization of Fe65Co35 but increasing both remanent magnetization and coercivityEls autors agraeixen el suport del MICINN-AEI a través del projecte NEXUS (PID2020-115215RB-C21 i PID2020-115215RB-C22). L'EMP agraeix el suport de l'AEI a través del programa Juan de la Cierva–Incorporación (beca IJC2020-043011-I/MCIN/AEI/10.13039/501100011033) i de la UE per NextGenerationEU/PRTR. L'IMDEA agraeix el suport del MICINN-AEI a través del Programa "Severo Ochoa" per a Centres d'Excel·lència en R+D (CEX2020-001039-S), i de la Comunitat de Madrid a través del projecte NANOMAGCOST (S2018/NMT-4321)Open Access funding provided thanks to the CRUE-CSIC agreement with WileyWiley2025info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionpeer-reviewedapplication/pdfhttp://hdl.handle.net/10256/26862http://hdl.handle.net/10256/26862Advanced Engineering Materials, 2025, vol. 27. núm. 6, p. 2402317Articles publicats (D-F)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)Inglésinfo:eu-repo/semantics/altIdentifier/doi/10.1002/adem.202402317info:eu-repo/semantics/altIdentifier/issn/1438-1656info:eu-repo/semantics/altIdentifier/eissn/1527-2648Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:recercat.cat:10256/268622026-05-29T05:05:01Z |
| dc.title.none.fl_str_mv |
Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic Properties |
| title |
Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic Properties |
| spellingShingle |
Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic Properties Daza Collier, Jason Aliatges Alloys Aliatge mecànic Mechanical alloying Ferro -- Aliatges Iron alloys Ferromagnetisme Ferromagnetism |
| title_short |
Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic Properties |
| title_full |
Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic Properties |
| title_fullStr |
Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic Properties |
| title_full_unstemmed |
Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic Properties |
| title_sort |
Effects of Processing Conditions of a Ball-Milled Fe65Co35 Soft Ferromagnetic Alloy on the Structural, Thermal, and Magnetic Properties |
| dc.creator.none.fl_str_mv |
Daza Collier, Jason Curbelo-Cano, Zaida Montero, Cristina M. Ben Mbarek, Wael Escoda i Acero, Ma. Lluïsa Saurina Canals, Joan Palmero, Ester M. Bollero, Alberto Bruna, Pere Suñol Martínez, Joan Josep |
| author |
Daza Collier, Jason |
| author_facet |
Daza Collier, Jason Curbelo-Cano, Zaida Montero, Cristina M. Ben Mbarek, Wael Escoda i Acero, Ma. Lluïsa Saurina Canals, Joan Palmero, Ester M. Bollero, Alberto Bruna, Pere Suñol Martínez, Joan Josep |
| author_role |
author |
| author2 |
Curbelo-Cano, Zaida Montero, Cristina M. Ben Mbarek, Wael Escoda i Acero, Ma. Lluïsa Saurina Canals, Joan Palmero, Ester M. Bollero, Alberto Bruna, Pere Suñol Martínez, Joan Josep |
| author2_role |
author author author author author author author author author |
| dc.subject.none.fl_str_mv |
Aliatges Alloys Aliatge mecànic Mechanical alloying Ferro -- Aliatges Iron alloys Ferromagnetisme Ferromagnetism |
| topic |
Aliatges Alloys Aliatge mecànic Mechanical alloying Ferro -- Aliatges Iron alloys Ferromagnetisme Ferromagnetism |
| description |
The Fe65Co35 alloy is a well-known Fe-based soft ferromagnetic alloy with excellent soft magnetic properties, which make it a strong candidate to be used in technological applications. In the present work, synthesizing nanoscrystalline Fe65Co35 alloy by mechanical alloying is focused on, adding cyclohexane (C6H12) acting as a process control agent (PCA). PCAs are effective in favoring nanostructured alloys with uniform grain size. The production of this type of alloy is a promising approach to tune the magnetic hardness in Fe65Co35. Structural, thermal, morphological, and magnetic properties have been studied after milling for 10, 25, and 50 h with and without the PCA. In the structural analysis, it is shown that the cubic α-Fe(Co) phase is the predominant phase in all samples. The use of the PCA favors its nanocrystallinity; however, it slows Co diffusion into the Fe matrix. Thermal analysis detects an endothermic process between 525 and 575 °C in the samples milled with C6H12 only. This is associated with the transition of the residual Fe3Co superlattice, to the stable α-Fe(Co). The effect of the residual Fe3Co at room temperature on the magnetic properties is twofold, by decreasing the saturation magnetization of Fe65Co35 but increasing both remanent magnetization and coercivity |
| publishDate |
2025 |
| dc.date.none.fl_str_mv |
2025 |
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info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion peer-reviewed |
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article |
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publishedVersion |
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http://hdl.handle.net/10256/26862 http://hdl.handle.net/10256/26862 |
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http://hdl.handle.net/10256/26862 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
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info:eu-repo/semantics/altIdentifier/doi/10.1002/adem.202402317 info:eu-repo/semantics/altIdentifier/issn/1438-1656 info:eu-repo/semantics/altIdentifier/eissn/1527-2648 |
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Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess |
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Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ |
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openAccess |
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application/pdf |
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Wiley |
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Wiley |
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Advanced Engineering Materials, 2025, vol. 27. núm. 6, p. 2402317 Articles publicats (D-F) reponame:Recercat. Dipósit de la Recerca de Catalunya instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
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Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
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Recercat. Dipósit de la Recerca de Catalunya |
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Recercat. Dipósit de la Recerca de Catalunya |
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