Opportunities for organocatalysis in polymer synthesis via step-growth methods

Organocatalysis has emerged as an invaluable tool for polymer synthesis and has already demonstrated versatility for replacing organometallic catalysts in many polymerization reactions. The overall ease of removal and lower toxicity of organocatalysts relative to their common metal counterparts has...

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Detalhes bibliográficos
Autores: Bossion, Amaury, Heifferon, Katherine V., Meabe Iturbe, Leire, Zivic, Nicholas, Taton, Daniel, Hedrick, James, Long, Timothy E., Sardon Muguruza, Haritz
Formato: artículo
Fecha de publicación:2019
País:España
Recursos:Universidad del País Vasco
Repositorio:Addi. Archivo Digital para la Docencia y la Investigación
OAI Identifier:oai:addi.ehu.eus:10810/31666
Acesso em linha:http://hdl.handle.net/10810/31666
Access Level:acceso abierto
Palavra-chave:polyurethanes
organocatalysis
step-growth
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spelling Opportunities for organocatalysis in polymer synthesis via step-growth methodsBossion, AmauryHeifferon, Katherine V.Meabe Iturbe, LeireZivic, NicholasTaton, DanielHedrick, JamesLong, Timothy E.Sardon Muguruza, Haritzpolyurethanesorganocatalysisstep-growthOrganocatalysis has emerged as an invaluable tool for polymer synthesis and has already demonstrated versatility for replacing organometallic catalysts in many polymerization reactions. The overall ease of removal and lower toxicity of organocatalysts relative to their common metal counterparts has also nurtured development especially in chain growth polymerizations to achieve precision macromolecular architectures for application in the biomedical space. The application of organocatalysts in step-growth polymerizations of polymers, including polyesters, polycarbonates, and polyurethanes, has garnered fewer studies in spite of the large array of benefits that could be achieved. Step-growth polymers account for nearly 20 wt. % of the Word Plastic Production and play a vital role in many technologies as engineering plastics and high performance polymeric materials with outstanding thermomechanical performance. Step-growth polymerizations are achieved using monomers with a diversity of chemical functionality. Consequently, a vast array of polymeric structures are attainable and will impact diverse applications in energy, aerospace, medicine, transportation, and construction. This review article will highlight the recent advances in organocatalysis in step growth polymerizations. We will primarily focus our review on the synthesis of commercially important polyesters and polyurethanes using organocatalysis, however, the review will also emphasize recent literature describing less explored polymers, such as polyethers, polycarbonates, and polybenzoins, which have recently employed organocatalysts. Moreover, the article will draw attention to recent efforts in the use of carbon dioxide as a monomer for the preparation of step-growth polymers in the presence of organocatalysis.The authors thank the European Commission for its financial support through the projects SUSPOL-EJD 642671. Haritz Sardon gratefully acknowledges financial support from MINECO through project MAT2017-83373-R.ElservierEuropean Commission201920192019info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10810/31666reponame:Addi. Archivo Digital para la Docencia y la Investigacióninstname:Universidad del País VascoInglésinfo:eu-repo/grantAgreement/EC/H2020/642671info:eu-repo/grantAgreement/MINECO/MAT2017-83373-R./https://www.sciencedirect.com/science/article/pii/S0079670018302764info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/(c) 2019 Elsevieroai:addi.ehu.eus:10810/316662026-06-18T09:23:17Z
dc.title.none.fl_str_mv Opportunities for organocatalysis in polymer synthesis via step-growth methods
title Opportunities for organocatalysis in polymer synthesis via step-growth methods
spellingShingle Opportunities for organocatalysis in polymer synthesis via step-growth methods
Bossion, Amaury
polyurethanes
organocatalysis
step-growth
title_short Opportunities for organocatalysis in polymer synthesis via step-growth methods
title_full Opportunities for organocatalysis in polymer synthesis via step-growth methods
title_fullStr Opportunities for organocatalysis in polymer synthesis via step-growth methods
title_full_unstemmed Opportunities for organocatalysis in polymer synthesis via step-growth methods
title_sort Opportunities for organocatalysis in polymer synthesis via step-growth methods
dc.creator.none.fl_str_mv Bossion, Amaury
Heifferon, Katherine V.
Meabe Iturbe, Leire
Zivic, Nicholas
Taton, Daniel
Hedrick, James
Long, Timothy E.
Sardon Muguruza, Haritz
author Bossion, Amaury
author_facet Bossion, Amaury
Heifferon, Katherine V.
Meabe Iturbe, Leire
Zivic, Nicholas
Taton, Daniel
Hedrick, James
Long, Timothy E.
Sardon Muguruza, Haritz
author_role author
author2 Heifferon, Katherine V.
Meabe Iturbe, Leire
Zivic, Nicholas
Taton, Daniel
Hedrick, James
Long, Timothy E.
Sardon Muguruza, Haritz
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv European Commission
dc.subject.none.fl_str_mv polyurethanes
organocatalysis
step-growth
topic polyurethanes
organocatalysis
step-growth
description Organocatalysis has emerged as an invaluable tool for polymer synthesis and has already demonstrated versatility for replacing organometallic catalysts in many polymerization reactions. The overall ease of removal and lower toxicity of organocatalysts relative to their common metal counterparts has also nurtured development especially in chain growth polymerizations to achieve precision macromolecular architectures for application in the biomedical space. The application of organocatalysts in step-growth polymerizations of polymers, including polyesters, polycarbonates, and polyurethanes, has garnered fewer studies in spite of the large array of benefits that could be achieved. Step-growth polymers account for nearly 20 wt. % of the Word Plastic Production and play a vital role in many technologies as engineering plastics and high performance polymeric materials with outstanding thermomechanical performance. Step-growth polymerizations are achieved using monomers with a diversity of chemical functionality. Consequently, a vast array of polymeric structures are attainable and will impact diverse applications in energy, aerospace, medicine, transportation, and construction. This review article will highlight the recent advances in organocatalysis in step growth polymerizations. We will primarily focus our review on the synthesis of commercially important polyesters and polyurethanes using organocatalysis, however, the review will also emphasize recent literature describing less explored polymers, such as polyethers, polycarbonates, and polybenzoins, which have recently employed organocatalysts. Moreover, the article will draw attention to recent efforts in the use of carbon dioxide as a monomer for the preparation of step-growth polymers in the presence of organocatalysis.
publishDate 2019
dc.date.none.fl_str_mv 2019
2019
2019
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10810/31666
url http://hdl.handle.net/10810/31666
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/grantAgreement/EC/H2020/642671
info:eu-repo/grantAgreement/MINECO/MAT2017-83373-R./
https://www.sciencedirect.com/science/article/pii/S0079670018302764
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
(c) 2019 Elsevier
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
(c) 2019 Elsevier
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elservier
publisher.none.fl_str_mv Elservier
dc.source.none.fl_str_mv reponame:Addi. Archivo Digital para la Docencia y la Investigación
instname:Universidad del País Vasco
instname_str Universidad del País Vasco
reponame_str Addi. Archivo Digital para la Docencia y la Investigación
collection Addi. Archivo Digital para la Docencia y la Investigación
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.300719

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