Valorization of olive oil industry subproducts: ash and olive pomace fast pyrolysis

Environmental problems have encouraged investigation of renewable energies. The organic waste treating through fast pyrolysis seems to be a highly promising option for decreasing pollutants. Olive pomace, a major source of waste in countries with high production of olive oil (mainly Spain, Italy, an...

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Autores: Alcazar Ruiz, Angel, Garcia-Carpintero, R., Dorado Fernández, Fernando, Sanchez-Silva, Luz
Tipo de recurso: artículo
Fecha de publicación:2021
País:España
Institución:Universidad de Castilla-La Mancha
Repositorio:RUIdeRA. Repositorio Institucional de la UCLM
OAI Identifier:oai:ruidera.uclm.es:10578/29862
Acceso en línea:http://hdl.handle.net/10578/29862
Access Level:acceso abierto
Palabra clave:Olive pomace
Subproduct valorization
Ash effect
Fast pyrolysis
Bio-Oil
Orujo de aceituna
Valorización de subproductos
Efecto ceniza
Pirólisis rápida
Bioaceite
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spelling Valorization of olive oil industry subproducts: ash and olive pomace fast pyrolysisAlcazar Ruiz, AngelGarcia-Carpintero, R.Dorado Fernández, FernandoSanchez-Silva, LuzOlive pomaceSubproduct valorizationAsh effectFast pyrolysisBio-OilOrujo de aceitunaValorización de subproductosEfecto cenizaPirólisis rápidaBioaceiteEnvironmental problems have encouraged investigation of renewable energies. The organic waste treating through fast pyrolysis seems to be a highly promising option for decreasing pollutants. Olive pomace, a major source of waste in countries with high production of olive oil (mainly Spain, Italy, and Greece), is a clear target for valorisation. Dried olive pomace together with the ashes obtained during the drying process was blended to study the influence of the inorganic metals inherently present in the ashes (K, Na, Ca and Mg) for fast pyrolysis product distribution. The results determined that these metals increased yields of phenolic compounds until a maximum was reached, whereas carboxylic acid yield fell due to the action of metals. In addition, aromatic hydrocarbons and polyphenols were obtained for those samples with a large amount of ash. Moreover, the formation of organic acids, such as acetic acid, requires a smaller proportion of ash in the blend. Finally, it has been found that the ashes could be used as a catalyst for producing better quality bio-oil, thereby avoiding extra costs and thus valorizing the industrial treatment olive pomace.Los problemas medioambientales han fomentado la investigación de las energías renovables. El tratamiento de residuos orgánicos mediante pirólisis rápida parece ser una opción muy prometedora para la disminución de contaminantes. El orujo de aceituna, una fuente importante de residuos en países con alta producción de aceite de oliva (principalmente España, Italia y Grecia), es un claro objetivo de valorización. El orujo de oliva seco junto con las cenizas obtenidas durante el proceso de secado se mezclaron para estudiar la influencia de los metales inorgánicos inherentemente presentes en las cenizas (K, Na, Ca y Mg) para una distribución rápida del producto de pirólisis. Los resultados determinaron que estos metales incrementaron los rendimientos de compuestos fenólicos hasta alcanzar un máximo, mientras que el rendimiento de ácidos carboxílicos disminuyó por la acción de los metales. Además, se obtuvieron hidrocarburos aromáticos y polifenoles para aquellas muestras con gran cantidad de ceniza. Además, la formación de ácidos orgánicos, como el ácido acético, requiere una menor proporción de cenizas en la mezcla. Finalmente, se ha comprobado que las cenizas podrían utilizarse como catalizador para producir bioaceite de mejor calidad, evitando así costes extras y valorizando así el tratamiento industrial del orujo de oliva.Elsevier202220222021info:eu-repo/semantics/articleapplication/pdfapplication/pdfhttp://hdl.handle.net/10578/29862reponame:RUIdeRA. Repositorio Institucional de la UCLMinstname:Universidad de Castilla-La ManchaInglésinfo:eu-repo/semantics/openAccessoai:ruidera.uclm.es:10578/298622026-05-27T07:36:41Z
dc.title.none.fl_str_mv Valorization of olive oil industry subproducts: ash and olive pomace fast pyrolysis
title Valorization of olive oil industry subproducts: ash and olive pomace fast pyrolysis
spellingShingle Valorization of olive oil industry subproducts: ash and olive pomace fast pyrolysis
Alcazar Ruiz, Angel
Olive pomace
Subproduct valorization
Ash effect
Fast pyrolysis
Bio-Oil
Orujo de aceituna
Valorización de subproductos
Efecto ceniza
Pirólisis rápida
Bioaceite
title_short Valorization of olive oil industry subproducts: ash and olive pomace fast pyrolysis
title_full Valorization of olive oil industry subproducts: ash and olive pomace fast pyrolysis
title_fullStr Valorization of olive oil industry subproducts: ash and olive pomace fast pyrolysis
title_full_unstemmed Valorization of olive oil industry subproducts: ash and olive pomace fast pyrolysis
title_sort Valorization of olive oil industry subproducts: ash and olive pomace fast pyrolysis
dc.creator.none.fl_str_mv Alcazar Ruiz, Angel
Garcia-Carpintero, R.
Dorado Fernández, Fernando
Sanchez-Silva, Luz
author Alcazar Ruiz, Angel
author_facet Alcazar Ruiz, Angel
Garcia-Carpintero, R.
Dorado Fernández, Fernando
Sanchez-Silva, Luz
author_role author
author2 Garcia-Carpintero, R.
Dorado Fernández, Fernando
Sanchez-Silva, Luz
author2_role author
author
author
dc.subject.none.fl_str_mv Olive pomace
Subproduct valorization
Ash effect
Fast pyrolysis
Bio-Oil
Orujo de aceituna
Valorización de subproductos
Efecto ceniza
Pirólisis rápida
Bioaceite
topic Olive pomace
Subproduct valorization
Ash effect
Fast pyrolysis
Bio-Oil
Orujo de aceituna
Valorización de subproductos
Efecto ceniza
Pirólisis rápida
Bioaceite
description Environmental problems have encouraged investigation of renewable energies. The organic waste treating through fast pyrolysis seems to be a highly promising option for decreasing pollutants. Olive pomace, a major source of waste in countries with high production of olive oil (mainly Spain, Italy, and Greece), is a clear target for valorisation. Dried olive pomace together with the ashes obtained during the drying process was blended to study the influence of the inorganic metals inherently present in the ashes (K, Na, Ca and Mg) for fast pyrolysis product distribution. The results determined that these metals increased yields of phenolic compounds until a maximum was reached, whereas carboxylic acid yield fell due to the action of metals. In addition, aromatic hydrocarbons and polyphenols were obtained for those samples with a large amount of ash. Moreover, the formation of organic acids, such as acetic acid, requires a smaller proportion of ash in the blend. Finally, it has been found that the ashes could be used as a catalyst for producing better quality bio-oil, thereby avoiding extra costs and thus valorizing the industrial treatment olive pomace.
publishDate 2021
dc.date.none.fl_str_mv 2021
2022
2022
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10578/29862
url http://hdl.handle.net/10578/29862
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:RUIdeRA. Repositorio Institucional de la UCLM
instname:Universidad de Castilla-La Mancha
instname_str Universidad de Castilla-La Mancha
reponame_str RUIdeRA. Repositorio Institucional de la UCLM
collection RUIdeRA. Repositorio Institucional de la UCLM
repository.name.fl_str_mv
repository.mail.fl_str_mv
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