Thermal evaluation of polymorphic transitions in layered hybrid organic-inorganic perovskites for energy storage applications

Layered hybrid organic-inorganic perovskites (LHOIPs) have gained specific attention in applications such as optoelectronics. However, from the thermal perspective, these materials present a high potential for thermal energy storage applications in solid-state due to their heat storage capacity duri...

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Autores: Salgado Pizarro, Rebeca, Navarro-Rivero, M. E., Ding, Y., Barreneche, Camila, Fernández Renna, Ana Inés
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2024
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/225073
Acceso en línea:https://hdl.handle.net/2445/225073
Access Level:acceso abierto
Palabra clave:Espectroscòpia Raman
Ciència dels materials
Emmagatzematge d'energia
Raman spectroscopy
Materials science
Storage of energy
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spelling Thermal evaluation of polymorphic transitions in layered hybrid organic-inorganic perovskites for energy storage applicationsSalgado Pizarro, RebecaNavarro-Rivero, M. E.Ding, Y.Barreneche, CamilaFernández Renna, Ana InésEspectroscòpia RamanCiència dels materialsEmmagatzematge d'energiaRaman spectroscopyMaterials scienceStorage of energyLayered hybrid organic-inorganic perovskites (LHOIPs) have gained specific attention in applications such as optoelectronics. However, from the thermal perspective, these materials present a high potential for thermal energy storage applications in solid-state due to their heat storage capacity during their phase transitions. Here, we evaluate the first-order transition of these materials from the molecular point of view and make a relation with organic size, which is responsible for the ordering-disordering transition. Six LHOIPs have been synthesised, (C12H25N)2CuCl4, (C14H29N)2CuCl4, (C16H33N)2CuCl4, (C12H24N)2MnCl4, (C14H29N)2MnCl4 and (C16H33N)2MnCl4, where the crystal transformation has been evaluated under X-ray diffraction and Raman, and thermal conductivity as well as the thermal expansion have been studied. This work provides a comprehensive evaluation of the disordering phenomenon that is produced during phase transitionsElsevier2025202520242025info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion8 p.application/pdfhttps://hdl.handle.net/2445/225073Articles publicats en revistes (Ciència dels Materials i Química Física)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésReproducció del document publicat a: https://doi.org/10.1016/j.est.2024.113483Journal Of Energy Storage, 2024, vol. 100https://doi.org/10.1016/j.est.2024.113483cc-by-nc-nd (c) Salgado Pizarro, Rebeca, et al., 2024http://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:recercat.cat:2445/2250732026-05-29T05:05:01Z
dc.title.none.fl_str_mv Thermal evaluation of polymorphic transitions in layered hybrid organic-inorganic perovskites for energy storage applications
title Thermal evaluation of polymorphic transitions in layered hybrid organic-inorganic perovskites for energy storage applications
spellingShingle Thermal evaluation of polymorphic transitions in layered hybrid organic-inorganic perovskites for energy storage applications
Salgado Pizarro, Rebeca
Espectroscòpia Raman
Ciència dels materials
Emmagatzematge d'energia
Raman spectroscopy
Materials science
Storage of energy
title_short Thermal evaluation of polymorphic transitions in layered hybrid organic-inorganic perovskites for energy storage applications
title_full Thermal evaluation of polymorphic transitions in layered hybrid organic-inorganic perovskites for energy storage applications
title_fullStr Thermal evaluation of polymorphic transitions in layered hybrid organic-inorganic perovskites for energy storage applications
title_full_unstemmed Thermal evaluation of polymorphic transitions in layered hybrid organic-inorganic perovskites for energy storage applications
title_sort Thermal evaluation of polymorphic transitions in layered hybrid organic-inorganic perovskites for energy storage applications
dc.creator.none.fl_str_mv Salgado Pizarro, Rebeca
Navarro-Rivero, M. E.
Ding, Y.
Barreneche, Camila
Fernández Renna, Ana Inés
author Salgado Pizarro, Rebeca
author_facet Salgado Pizarro, Rebeca
Navarro-Rivero, M. E.
Ding, Y.
Barreneche, Camila
Fernández Renna, Ana Inés
author_role author
author2 Navarro-Rivero, M. E.
Ding, Y.
Barreneche, Camila
Fernández Renna, Ana Inés
author2_role author
author
author
author
dc.subject.none.fl_str_mv Espectroscòpia Raman
Ciència dels materials
Emmagatzematge d'energia
Raman spectroscopy
Materials science
Storage of energy
topic Espectroscòpia Raman
Ciència dels materials
Emmagatzematge d'energia
Raman spectroscopy
Materials science
Storage of energy
description Layered hybrid organic-inorganic perovskites (LHOIPs) have gained specific attention in applications such as optoelectronics. However, from the thermal perspective, these materials present a high potential for thermal energy storage applications in solid-state due to their heat storage capacity during their phase transitions. Here, we evaluate the first-order transition of these materials from the molecular point of view and make a relation with organic size, which is responsible for the ordering-disordering transition. Six LHOIPs have been synthesised, (C12H25N)2CuCl4, (C14H29N)2CuCl4, (C16H33N)2CuCl4, (C12H24N)2MnCl4, (C14H29N)2MnCl4 and (C16H33N)2MnCl4, where the crystal transformation has been evaluated under X-ray diffraction and Raman, and thermal conductivity as well as the thermal expansion have been studied. This work provides a comprehensive evaluation of the disordering phenomenon that is produced during phase transitions
publishDate 2024
dc.date.none.fl_str_mv 2024
2025
2025
2025
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/225073
url https://hdl.handle.net/2445/225073
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Reproducció del document publicat a: https://doi.org/10.1016/j.est.2024.113483
Journal Of Energy Storage, 2024, vol. 100
https://doi.org/10.1016/j.est.2024.113483
dc.rights.none.fl_str_mv cc-by-nc-nd (c) Salgado Pizarro, Rebeca, et al., 2024
http://creativecommons.org/licenses/by-nc-nd/4.0/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv cc-by-nc-nd (c) Salgado Pizarro, Rebeca, et al., 2024
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 8 p.
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv Articles publicats en revistes (Ciència dels Materials i Química Física)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869420267287085056
score 15,811543

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