Photocatalytic magnetic microgyroscopes with activity-tunable precessional dynamics

Magnetic nano/microrotors are passive elements spinning around an axis due to an external rotating field while remaining confined to a plane. They have been used to date in different applications related to fluid mixing, drug delivery, or biomedicine. Here we realize an active version of a magnetic...

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Detalles Bibliográficos
Autores: Boniface, Dolachai, Straube, Arthur V., Tierno, Pietro
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2024
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/218514
Acceso en línea:https://hdl.handle.net/2445/218514
Access Level:acceso abierto
Palabra clave:Propietats magnètiques
Col·loides
Nanopartícules
Magnetic properties
Colloids
Nanoparticles
Descripción
Sumario:Magnetic nano/microrotors are passive elements spinning around an axis due to an external rotating field while remaining confined to a plane. They have been used to date in different applications related to fluid mixing, drug delivery, or biomedicine. Here we realize an active version of a magnetic microgyroscope which is simultaneously driven by a photoactivated catalytic reaction and a rotating magnetic field. We investigate the uplift dynamics of this colloidal spinner when it precesses around its long axis while self-propelling due to the light induced decomposition of hydrogen peroxide in water. By combining experiments with theory, we show that activity emerging from the cooperative action of phoretic and osmotic forces effectively increases the gravitational torque, which counteracts the magnetic and viscous ones, and carefully measure its contribution. Finally, we demonstrate that by modulating the field amplitude, one can induce hysteresis loops in the uplift dynamics of the spinners.