A fast synthesis route of boron-carbon-nitrogen ultrathin layers towards highly mixed ternary B-C-N phases

We report a direct and fast synthesis route to grow boron-carbon-nitrogen layers based on microwave-assisted plasma enhanced chemical vapour deposition (PECVD) by using methylamine borane as a single source molecular precursor. This easy and inexpensive method allows controlled and reproducible grow...

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Autores: Leardini, Fabrice, Jiménez-Arévalo, Nuria, Jiménez Ferrer, M. Isabel, Ares Fernández, José Ramón, Molina de Pablo, Pablo, Navarro, Cristina Gómez, Manzanares, Yolanda, Granados, Daniel, Urbanos, Fernando J., Garcia-Garcia, F. Javier, Del Campo, Adolfo, Avvisati, Giulia, Betti, Maria Grazia, Mariani, Carlo
Tipo de recurso: artículo
Fecha de publicación:2019
País:España
Institución:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/705950
Acceso en línea:http://hdl.handle.net/10486/705950
https://dx.doi.org/10.1088/2053-1583/ab175c
Access Level:acceso abierto
Palabra clave:Raman spectroscopy
Borocarbonitride
Optical Bandgap
Electronic Transport Measurements
Plasma-Enhanced Chemical Vapor Deposition
Transmission Electron Microscopy
X-Ray Photoelectron Spectroscopy
Física
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spelling A fast synthesis route of boron-carbon-nitrogen ultrathin layers towards highly mixed ternary B-C-N phasesLeardini, FabriceJiménez-Arévalo, NuriaJiménez Ferrer, M. IsabelAres Fernández, José RamónMolina de Pablo, PabloNavarro, Cristina GómezManzanares, YolandaGranados, DanielUrbanos, Fernando J.Garcia-Garcia, F. JavierDel Campo, AdolfoAvvisati, GiuliaBetti, Maria GraziaMariani, CarloRaman spectroscopyBorocarbonitrideOptical BandgapElectronic Transport MeasurementsPlasma-Enhanced Chemical Vapor DepositionTransmission Electron MicroscopyX-Ray Photoelectron SpectroscopyFísicaWe report a direct and fast synthesis route to grow boron-carbon-nitrogen layers based on microwave-assisted plasma enhanced chemical vapour deposition (PECVD) by using methylamine borane as a single source molecular precursor. This easy and inexpensive method allows controlled and reproducible growth of B-C-N layers onto thin Cu foils. Their morphological, structural, chemical, optical and transport properties have been thoroughly characterized by a number of different microscopies, transport and spectroscopic techniques. Though disorder and segregation into C-rich and h-BN-rich domains have been observed in ultrathin flat few layers, high doping levels have been reached, inducing strong modifications of the electronic, optical and transport properties of C-rich and h-BN-rich phases. This synthesis procedure can open new routes towards the achievement of homogeneous highly mixed ternary B-C-N phasesIOP PublishingDepartamento de Física de la Materia CondensadaDepartamento de Física de MaterialesFacultad de Ciencias20192019-05-02research articlehttp://purl.org/coar/resource_type/c_2df8fbb1AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10486/705950https://dx.doi.org/10.1088/2053-1583/ab175creponame:Biblos-e Archivo. Repositorio Institucional de la UAMinstname:Universidad Autónoma de MadridInglésengopen accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:repositorio.uam.es:10486/7059502026-06-23T12:46:27Z
dc.title.none.fl_str_mv A fast synthesis route of boron-carbon-nitrogen ultrathin layers towards highly mixed ternary B-C-N phases
title A fast synthesis route of boron-carbon-nitrogen ultrathin layers towards highly mixed ternary B-C-N phases
spellingShingle A fast synthesis route of boron-carbon-nitrogen ultrathin layers towards highly mixed ternary B-C-N phases
Leardini, Fabrice
Raman spectroscopy
Borocarbonitride
Optical Bandgap
Electronic Transport Measurements
Plasma-Enhanced Chemical Vapor Deposition
Transmission Electron Microscopy
X-Ray Photoelectron Spectroscopy
Física
title_short A fast synthesis route of boron-carbon-nitrogen ultrathin layers towards highly mixed ternary B-C-N phases
title_full A fast synthesis route of boron-carbon-nitrogen ultrathin layers towards highly mixed ternary B-C-N phases
title_fullStr A fast synthesis route of boron-carbon-nitrogen ultrathin layers towards highly mixed ternary B-C-N phases
title_full_unstemmed A fast synthesis route of boron-carbon-nitrogen ultrathin layers towards highly mixed ternary B-C-N phases
title_sort A fast synthesis route of boron-carbon-nitrogen ultrathin layers towards highly mixed ternary B-C-N phases
dc.creator.none.fl_str_mv Leardini, Fabrice
Jiménez-Arévalo, Nuria
Jiménez Ferrer, M. Isabel
Ares Fernández, José Ramón
Molina de Pablo, Pablo
Navarro, Cristina Gómez
Manzanares, Yolanda
Granados, Daniel
Urbanos, Fernando J.
Garcia-Garcia, F. Javier
Del Campo, Adolfo
Avvisati, Giulia
Betti, Maria Grazia
Mariani, Carlo
author Leardini, Fabrice
author_facet Leardini, Fabrice
Jiménez-Arévalo, Nuria
Jiménez Ferrer, M. Isabel
Ares Fernández, José Ramón
Molina de Pablo, Pablo
Navarro, Cristina Gómez
Manzanares, Yolanda
Granados, Daniel
Urbanos, Fernando J.
Garcia-Garcia, F. Javier
Del Campo, Adolfo
Avvisati, Giulia
Betti, Maria Grazia
Mariani, Carlo
author_role author
author2 Jiménez-Arévalo, Nuria
Jiménez Ferrer, M. Isabel
Ares Fernández, José Ramón
Molina de Pablo, Pablo
Navarro, Cristina Gómez
Manzanares, Yolanda
Granados, Daniel
Urbanos, Fernando J.
Garcia-Garcia, F. Javier
Del Campo, Adolfo
Avvisati, Giulia
Betti, Maria Grazia
Mariani, Carlo
author2_role author
author
author
author
author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Física de la Materia Condensada
Departamento de Física de Materiales
Facultad de Ciencias
dc.subject.none.fl_str_mv Raman spectroscopy
Borocarbonitride
Optical Bandgap
Electronic Transport Measurements
Plasma-Enhanced Chemical Vapor Deposition
Transmission Electron Microscopy
X-Ray Photoelectron Spectroscopy
Física
topic Raman spectroscopy
Borocarbonitride
Optical Bandgap
Electronic Transport Measurements
Plasma-Enhanced Chemical Vapor Deposition
Transmission Electron Microscopy
X-Ray Photoelectron Spectroscopy
Física
description We report a direct and fast synthesis route to grow boron-carbon-nitrogen layers based on microwave-assisted plasma enhanced chemical vapour deposition (PECVD) by using methylamine borane as a single source molecular precursor. This easy and inexpensive method allows controlled and reproducible growth of B-C-N layers onto thin Cu foils. Their morphological, structural, chemical, optical and transport properties have been thoroughly characterized by a number of different microscopies, transport and spectroscopic techniques. Though disorder and segregation into C-rich and h-BN-rich domains have been observed in ultrathin flat few layers, high doping levels have been reached, inducing strong modifications of the electronic, optical and transport properties of C-rich and h-BN-rich phases. This synthesis procedure can open new routes towards the achievement of homogeneous highly mixed ternary B-C-N phases
publishDate 2019
dc.date.none.fl_str_mv 2019
2019-05-02
dc.type.none.fl_str_mv research article
http://purl.org/coar/resource_type/c_2df8fbb1
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10486/705950
https://dx.doi.org/10.1088/2053-1583/ab175c
url http://hdl.handle.net/10486/705950
https://dx.doi.org/10.1088/2053-1583/ab175c
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv IOP Publishing
publisher.none.fl_str_mv IOP Publishing
dc.source.none.fl_str_mv reponame:Biblos-e Archivo. Repositorio Institucional de la UAM
instname:Universidad Autónoma de Madrid
instname_str Universidad Autónoma de Madrid
reponame_str Biblos-e Archivo. Repositorio Institucional de la UAM
collection Biblos-e Archivo. Repositorio Institucional de la UAM
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869420059102806016
score 15,301603

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