Nanostructured stainless steel wire mesh-supported CdxZn1 − xO: A stable photocatalyst under visible and ultraviolet irradiation

In this work, high surface area stainless steel wire mesh-supported CdxZn1 − xO catalysts (x = 0.01–0.20) were successfully synthesized and tested for the photodegradation of methylene blue under UV and visible light. The solid solution, prepared at low temperature by means of sacrificial template a...

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Detalles Bibliográficos
Autores: Vu, Thi Tan, Rodil, Ana B., Marbán Calzón, Gregorio, Valdés-Solís Iglesias, Teresa
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2014
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/111033
Acceso en línea:http://hdl.handle.net/10261/111033
Access Level:acceso abierto
Palabra clave:ZnO
CdxZn1 − xO solid solution
Sacrificial template
Photocatalysis
Methylene blue
Descripción
Sumario:In this work, high surface area stainless steel wire mesh-supported CdxZn1 − xO catalysts (x = 0.01–0.20) were successfully synthesized and tested for the photodegradation of methylene blue under UV and visible light. The solid solution, prepared at low temperature by means of sacrificial template accelerated hydrolysis, shows a cadmium concentration profile in which the external surface contains more cadmium than the bulk and a maximum average cadmium content of 20 mol%. The presence of the cadmium in the catalyst protects the photocatalyst against photocorrosion. Under visible irradiation both undoped and doped catalysts show significant degrees of catalytic activity and stability.