High surface area stainless steel wire mesh-supported TiO2 prepared by sacrificial template accelerated hydrolysis. A monolithic photocatalyst superior to P25 TiO2

High surface area stainless steel wire mesh-supported TiO2 catalysts were prepared by sacrificial template accelerated hydrolysis using highly polar stainless steel wire mesh-supported ZnO templates. The monolithic catalysts were tested for the photodegradation of methylene blue in aqueous solution...

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Detalles Bibliográficos
Autores: Vu, Thi Tan, Valdés-Solís Iglesias, Teresa, Marbán Calzón, Gregorio
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2014
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/111038
Acceso en línea:http://hdl.handle.net/10261/111038
Access Level:acceso abierto
Palabra clave:TiO2
Sacrificial template
Photodegradation
Methylene blue
P25 TiO2
Descripción
Sumario:High surface area stainless steel wire mesh-supported TiO2 catalysts were prepared by sacrificial template accelerated hydrolysis using highly polar stainless steel wire mesh-supported ZnO templates. The monolithic catalysts were tested for the photodegradation of methylene blue in aqueous solution under ultraviolet irradiation. The calcination temperature of the catalysts was observed to have a determinant effect on their catalytic activity. The optimum calcination temperature range was 450–600 °C, in which a combination of high surface area (50–90 m2 g−1), a high degree of crystallinity and a minimum rutile content yielded the best catalytic results, with maximum catalytic activity appearing for a calcination temperature of 450 °C. The most active catalyst prepared in this work displayed twice the catalytic activity of the reference catalyst, P25 TiO2.