Aromaticidad molecular = Molecular aromaticity
Molecular aromaticity, like so many other basic notions in chemistry, is not a well-defined concept due to its unobservable nature. Despite its imprecise nature, it is a concept of utmost importance. In this review, we first briefly review the history of aromaticity and its quantum nature. We demons...
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| Format: | article |
| Status: | Published version |
| Publication Date: | 2025 |
| Country: | España |
| Institution: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repository: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:10256/28021 |
| Online Access: | http://hdl.handle.net/10256/28021 |
| Access Level: | Open access |
| Keyword: | Aromaticitat (Química) Aromaticity (Chemistry) |
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Aromaticidad molecular = Molecular aromaticitySolà i Puig, MiquelAromaticitat (Química)Aromaticity (Chemistry)Molecular aromaticity, like so many other basic notions in chemistry, is not a well-defined concept due to its unobservable nature. Despite its imprecise nature, it is a concept of utmost importance. In this review, we first briefly review the history of aromaticity and its quantum nature. We demonstrate that, despite the lack of a precise definition, several very simple electron-counting rules exist that are followed by a large number of organic and inorganic aromatic compounds. Finally, we comment on the main types of aromaticity and analyze the most common ways of quantifying aromaticity, highlighting the fact that different descriptors do not speak always with the same voiceLa aromaticidad molecular, como tantas otras nociones básicas en química, no es un concepto bien definido debido a su naturaleza no observable. A pesar de su carácter impreciso, es un concepto de gran importancia. En esta revisión, analizamos primero y de forma breve la historia de la aromaticidad, su naturaleza cuántica, y demostramos que, a pesar de la falta de una definición precisa, existen varias reglas de conteo de electrones muy simples que siguen un gran número de compuestos aromáticos orgánicos e inorgánicos. Finalmente, presentamos los tipos principales de aromaticidad y analizamos las formas más habituales de cuantificar la aromaticidad, destacando el hecho que los diferentes descriptores no siempre producen los mismos resultadosAgencia Española de Investigación (MICIU/AEI/10.13039/501100011033) por el proyecto PID2023-147424NB-I00 y a la Generalitat de Catalunya por el proyecto 2021SGR623 y el premio ICREA Academia 2024Real Sociedad Española de QuímicaAgencia Estatal de Investigación2025info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionpeer-reviewedapplication/pdfhttp://hdl.handle.net/10256/28021http://hdl.handle.net/10256/28021Anales de Química de la RSEQ, 2025, vol. 121, núm. 4, p.277-286Articles publicats (D-Q)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)Españolinfo:eu-repo/semantics/altIdentifier/doi/10.62534/rseq.aq.2086info:eu-repo/semantics/altIdentifier/issn/2792-520Xinfo:eu-repo/semantics/altIdentifier/eissn/2792-5250PID2023-147424NB-I00info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2023-147424NB-I00Attribution-NonCommercial-ShareAlike 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-sa/4.0/info:eu-repo/semantics/openAccessoai:recercat.cat:10256/280212026-05-29T05:05:01Z |
| dc.title.none.fl_str_mv |
Aromaticidad molecular = Molecular aromaticity |
| title |
Aromaticidad molecular = Molecular aromaticity |
| spellingShingle |
Aromaticidad molecular = Molecular aromaticity Solà i Puig, Miquel Aromaticitat (Química) Aromaticity (Chemistry) |
| title_short |
Aromaticidad molecular = Molecular aromaticity |
| title_full |
Aromaticidad molecular = Molecular aromaticity |
| title_fullStr |
Aromaticidad molecular = Molecular aromaticity |
| title_full_unstemmed |
Aromaticidad molecular = Molecular aromaticity |
| title_sort |
Aromaticidad molecular = Molecular aromaticity |
| dc.creator.none.fl_str_mv |
Solà i Puig, Miquel |
| author |
Solà i Puig, Miquel |
| author_facet |
Solà i Puig, Miquel |
| author_role |
author |
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Agencia Estatal de Investigación |
| dc.subject.none.fl_str_mv |
Aromaticitat (Química) Aromaticity (Chemistry) |
| topic |
Aromaticitat (Química) Aromaticity (Chemistry) |
| description |
Molecular aromaticity, like so many other basic notions in chemistry, is not a well-defined concept due to its unobservable nature. Despite its imprecise nature, it is a concept of utmost importance. In this review, we first briefly review the history of aromaticity and its quantum nature. We demonstrate that, despite the lack of a precise definition, several very simple electron-counting rules exist that are followed by a large number of organic and inorganic aromatic compounds. Finally, we comment on the main types of aromaticity and analyze the most common ways of quantifying aromaticity, highlighting the fact that different descriptors do not speak always with the same voice |
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2025 |
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2025 |
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info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion peer-reviewed |
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article |
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http://hdl.handle.net/10256/28021 http://hdl.handle.net/10256/28021 |
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http://hdl.handle.net/10256/28021 |
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Español |
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Español |
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info:eu-repo/semantics/altIdentifier/doi/10.62534/rseq.aq.2086 info:eu-repo/semantics/altIdentifier/issn/2792-520X info:eu-repo/semantics/altIdentifier/eissn/2792-5250 PID2023-147424NB-I00 info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2023-147424NB-I00 |
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Attribution-NonCommercial-ShareAlike 4.0 International http://creativecommons.org/licenses/by-nc-sa/4.0/ info:eu-repo/semantics/openAccess |
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Attribution-NonCommercial-ShareAlike 4.0 International http://creativecommons.org/licenses/by-nc-sa/4.0/ |
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openAccess |
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application/pdf |
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Real Sociedad Española de Química |
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Real Sociedad Española de Química |
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Anales de Química de la RSEQ, 2025, vol. 121, núm. 4, p.277-286 Articles publicats (D-Q) reponame:Recercat. Dipósit de la Recerca de Catalunya instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
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Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
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Recercat. Dipósit de la Recerca de Catalunya |
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Recercat. Dipósit de la Recerca de Catalunya |
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