Aromaticity of all-metal clusters

The first all-metal aromatic cluster, Al42-, face-capped by an M+ cation (M = Li, Na, Cu), was detected in 2001. Since then, several all-metal aromatic clusters have been extensively studied. Here, we review the most significant developments that have occurred mainly in our labs, including topics ra...

Descripción completa

Detalles Bibliográficos
Autores: Solà i Puig, Miquel, Muñoz-Castro, Alvaro
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:10256/27511
Acceso en línea:http://hdl.handle.net/10256/27511
Access Level:acceso abierto
Palabra clave:Compostos aromàtics
Aromatic compounds
Aromaticitat (Química)
Aromaticity (Chemistry)
Descripción
Sumario:The first all-metal aromatic cluster, Al42-, face-capped by an M+ cation (M = Li, Na, Cu), was detected in 2001. Since then, several all-metal aromatic clusters have been extensively studied. Here, we review the most significant developments that have occurred mainly in our labs, including topics ranging from the difficulty of measuring aromaticity in metal clusters to the use of current techniques to investigate aromaticity in both small and large metal clusters