Direct Dual-Template Synthesis of MWW Zeolite Monolayers
A two-dimensional zeolite with the topol. of MWW sheets has been obtained by direct synthesis with a combination of two org. structure-directing agents. The resultant material consists of approx. 70 % single and double layers and displays a well-structured external surface area of about 300 m2 g-1....
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2015 |
| País: | España |
| Institución: | Universitat Politècnica de València (UPV) |
| Repositorio: | RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia |
| Idioma: | inglés |
| OAI Identifier: | oai:riunet.upv.es:10251/77648 |
| Acceso en línea: | https://riunet.upv.es/handle/10251/77648 |
| Access Level: | acceso abierto |
| Palabra clave: | alkylation cumene heterogeneous catalysis organic structure-directing agents zeolites QUIMICA ORGANICA |
| Sumario: | A two-dimensional zeolite with the topol. of MWW sheets has been obtained by direct synthesis with a combination of two org. structure-directing agents. The resultant material consists of approx. 70 % single and double layers and displays a well-structured external surface area of about 300 m2 g-1. The delaminated zeolite prepd. by means of this single-step synthetic route has a high delamination degree, and the structural integrity of the MWW layers is well preserved. The new zeolite material displayed excellent activity, selectivity, and stability when used as a catalyst for the alkylation of benzene with propylene and found to be superior to the catalysts that are currently used for producing cumene. |
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