Metal-Catalyzed annulations through activation and cleavage of C−H bonds

The exponential increase in the number of catalytic transformations that involve a metal-promoted activation of hitherto considered inert C−H bonds is promoting a fundamental change in the field of synthetic chemistry. Although most reactions involving C−H activations consist of simple functionaliza...

Descripción completa

Detalles Bibliográficos
Autores: Gulías Costa, Moisés, Mascareñas Cid, José Luis
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Universidad de Santiago de Compostela (USC)
Repositorio:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
Idioma:inglés
OAI Identifier:oai:minerva.usc.gal:10347/14870
Acceso en línea:http://hdl.handle.net/10347/14870
Access Level:acceso abierto
Palabra clave:Materias::Investigación::23 Química::2302 Bioquímica
id ES_c99b4e14819a6ed1c0170ddc7e73bb8e
oai_identifier_str oai:minerva.usc.gal:10347/14870
network_acronym_str ES
network_name_str España
repository_id_str
spelling Metal-Catalyzed annulations through activation and cleavage of C−H bondsGulías Costa, MoisésMascareñas Cid, José LuisMaterias::Investigación::23 Química::2302 BioquímicaThe exponential increase in the number of catalytic transformations that involve a metal-promoted activation of hitherto considered inert C−H bonds is promoting a fundamental change in the field of synthetic chemistry. Although most reactions involving C−H activations consist of simple functionalizations or additions, recent years have witnessed an upsurge in related transformations that can be formally considered as cycloaddition processes. These transformations are particularly appealing from a synthetic perspective because they allow the conversion of readily available substrates into highly valuable cyclic products in a rapid and sustainable manner. In many cases, these annulations involve the formation of metallacyclic intermediates that resemble those proposed for standard metal-catalyzed cycloadditions of unsaturated precursorsWILEY-VCH Verlag GmbHUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais MolecularesUniversidade de Santiago de Compostela. Departamento de Química Orgánica20162016-06-2220162016-06-22journal articlehttp://purl.org/coar/resource_type/c_6501AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10347/14870reponame:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostelainstname:Universidad de Santiago de Compostela (USC)InglésengEuropean Commission http://dx.doi.org/10.13039/501100000780 Seventh Framework Programme 340055Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016 SAF2013-41943-R HERRAMIENTAS SINTETICAS EN QUIMICA BIOLOGICA. NUEVAS ESTRATEGIAS MOLECULARES PARA EL TRATAMIENTO Y DIAGNOSTICO DE CANCERESopen accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:minerva.usc.gal:10347/148702026-06-15T12:47:27Z
dc.title.none.fl_str_mv Metal-Catalyzed annulations through activation and cleavage of C−H bonds
title Metal-Catalyzed annulations through activation and cleavage of C−H bonds
spellingShingle Metal-Catalyzed annulations through activation and cleavage of C−H bonds
Gulías Costa, Moisés
Materias::Investigación::23 Química::2302 Bioquímica
title_short Metal-Catalyzed annulations through activation and cleavage of C−H bonds
title_full Metal-Catalyzed annulations through activation and cleavage of C−H bonds
title_fullStr Metal-Catalyzed annulations through activation and cleavage of C−H bonds
title_full_unstemmed Metal-Catalyzed annulations through activation and cleavage of C−H bonds
title_sort Metal-Catalyzed annulations through activation and cleavage of C−H bonds
dc.creator.none.fl_str_mv Gulías Costa, Moisés
Mascareñas Cid, José Luis
author Gulías Costa, Moisés
author_facet Gulías Costa, Moisés
Mascareñas Cid, José Luis
author_role author
author2 Mascareñas Cid, José Luis
author2_role author
dc.contributor.none.fl_str_mv Universidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculares
Universidade de Santiago de Compostela. Departamento de Química Orgánica
dc.subject.none.fl_str_mv Materias::Investigación::23 Química::2302 Bioquímica
topic Materias::Investigación::23 Química::2302 Bioquímica
description The exponential increase in the number of catalytic transformations that involve a metal-promoted activation of hitherto considered inert C−H bonds is promoting a fundamental change in the field of synthetic chemistry. Although most reactions involving C−H activations consist of simple functionalizations or additions, recent years have witnessed an upsurge in related transformations that can be formally considered as cycloaddition processes. These transformations are particularly appealing from a synthetic perspective because they allow the conversion of readily available substrates into highly valuable cyclic products in a rapid and sustainable manner. In many cases, these annulations involve the formation of metallacyclic intermediates that resemble those proposed for standard metal-catalyzed cycloadditions of unsaturated precursors
publishDate 2016
dc.date.none.fl_str_mv 2016
2016-06-22
2016
2016-06-22
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10347/14870
url http://hdl.handle.net/10347/14870
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv European Commission http://dx.doi.org/10.13039/501100000780 Seventh Framework Programme 340055
Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016 SAF2013-41943-R HERRAMIENTAS SINTETICAS EN QUIMICA BIOLOGICA. NUEVAS ESTRATEGIAS MOLECULARES PARA EL TRATAMIENTO Y DIAGNOSTICO DE CANCERES
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv WILEY-VCH Verlag GmbH
publisher.none.fl_str_mv WILEY-VCH Verlag GmbH
dc.source.none.fl_str_mv reponame:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
instname:Universidad de Santiago de Compostela (USC)
instname_str Universidad de Santiago de Compostela (USC)
reponame_str Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
collection Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869419385168330752
score 15.811543

Similares en LA Referencia