Green extraction of phenolic compounds and carotenoids from the pulp and peel of mango criollo by sustainable emerging technologies

This work offers a side-by-side overview of the behaviour of two liquors obtained via two fractionation processes, ionosolv and organosolv, from Eucalyptus globulus wood, and how the precipitation strategy that follows may affect the final yield, morphology, and particle size of every kind of lignin...

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Authors: Rodríguez Rodríguez, Elena, Ojeda, Gonzalo Adrián, Sgroppo, Sonia Cecilia, Olmedilla Alonso, Begoña, Sánchez-Moreno, Concepción, Sánchez Prieto, Milagros, Giménez, Lucía, Núñez Flores, Ruth, Ancos, Begoña de
Format: article
Publication Date:2025
Country:España
Institution:Universidad Complutense de Madrid (UCM)
Repository:Docta Complutense
Language:English
OAI Identifier:oai:docta.ucm.es:20.500.14352/131573
Online Access:https://hdl.handle.net/20.500.14352/131573
Access Level:Open access
Keyword:615:54
615.31
Química analítica (Farmacia)
2301 Química Analítica
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spelling Green extraction of phenolic compounds and carotenoids from the pulp and peel of mango criollo by sustainable emerging technologiesRodríguez Rodríguez, ElenaOjeda, Gonzalo AdriánSgroppo, Sonia CeciliaOlmedilla Alonso, BegoñaSánchez-Moreno, ConcepciónSánchez Prieto, MilagrosGiménez, LucíaNúñez Flores, RuthAncos, Begoña de615:54615.31Química analítica (Farmacia)2301 Química AnalíticaThis work offers a side-by-side overview of the behaviour of two liquors obtained via two fractionation processes, ionosolv and organosolv, from Eucalyptus globulus wood, and how the precipitation strategy that follows may affect the final yield, morphology, and particle size of every kind of lignin nanoparticle. For lignin nanoparticle precipitation, two bottom-up techniques and two top-down approaches were employed to determine which combination of fractionation process and synthesis treatment would provide the nanoparticles with the best characteristics. The results demonstrated the importance of the fractionation process in the final lignin nanoparticle yield, as ionosolv fractionation gave enhanced yields of more than 60% lignin in the form of nanoparticles. However, sphericity, particle sizes, and non-agglomerated structures were easily obtained from organosolv liquors, in which precipitation was carried out progressively in the absence of sonication. The use of ultrasound mostly resulted in the breakage of particles into smaller and irregular pieces. However, in the case of ionosolv liquors, homogeneous spherical nanoparticles were fused, forming agglomerates of smaller particles through the top-down strategy of complete addition of the antisolvent followed by sonication. The highest precipitation yield of nanoparticles was obtained from ionosolv liquors in which the full amount of antisolvent was added in one step to precipitate lignin, and then sonication was applied. In contrast, the lignin nanoparticles (LNPs) precipitation strategy that resulted in more spherical LNPs was the bottom-up strategy of precipitation by progressive antisolvent addition, resulting in visually observed non-aggregated spherical particles with a particle size distribution of 200 nm < dp < 500 nm, molecular weight of Mw = 14 000 g mol−1 , and thermal degradation property of T10% = 310 °C.The Royal Society of ChemistryUniversidad Complutense de Madrid20252025-01-0120252025-01-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/20.500.14352/131573reponame:Docta Complutenseinstname:Universidad Complutense de Madrid (UCM)InglésengAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020 PID2020-113570RB-I00 BIORREFINERIA INTEGRADA DE MADERA Y HUESOS DE FRUTAS: ESCALADO, FORMULACION DE BIOPRODUCTOS Y ANALISIS TECNOECONOMICOAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2021-124231OB-I00 EXTRACCION BIFASICA ACUOSA PARA LA RECUPERACION Y REUTILIZACION DE LIQUIDOS IONICOS AGUAS ABAJO DE LOS PROCESOS DE BIORREFINERIA ()open accesshttp://purl.org/coar/access_right/c_abf2Attribution 4.0 Internationalhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:docta.ucm.es:20.500.14352/1315732026-06-02T12:44:21Z
dc.title.none.fl_str_mv Green extraction of phenolic compounds and carotenoids from the pulp and peel of mango criollo by sustainable emerging technologies
title Green extraction of phenolic compounds and carotenoids from the pulp and peel of mango criollo by sustainable emerging technologies
spellingShingle Green extraction of phenolic compounds and carotenoids from the pulp and peel of mango criollo by sustainable emerging technologies
Rodríguez Rodríguez, Elena
615:54
615.31
Química analítica (Farmacia)
2301 Química Analítica
title_short Green extraction of phenolic compounds and carotenoids from the pulp and peel of mango criollo by sustainable emerging technologies
title_full Green extraction of phenolic compounds and carotenoids from the pulp and peel of mango criollo by sustainable emerging technologies
title_fullStr Green extraction of phenolic compounds and carotenoids from the pulp and peel of mango criollo by sustainable emerging technologies
title_full_unstemmed Green extraction of phenolic compounds and carotenoids from the pulp and peel of mango criollo by sustainable emerging technologies
title_sort Green extraction of phenolic compounds and carotenoids from the pulp and peel of mango criollo by sustainable emerging technologies
dc.creator.none.fl_str_mv Rodríguez Rodríguez, Elena
Ojeda, Gonzalo Adrián
Sgroppo, Sonia Cecilia
Olmedilla Alonso, Begoña
Sánchez-Moreno, Concepción
Sánchez Prieto, Milagros
Giménez, Lucía
Núñez Flores, Ruth
Ancos, Begoña de
author Rodríguez Rodríguez, Elena
author_facet Rodríguez Rodríguez, Elena
Ojeda, Gonzalo Adrián
Sgroppo, Sonia Cecilia
Olmedilla Alonso, Begoña
Sánchez-Moreno, Concepción
Sánchez Prieto, Milagros
Giménez, Lucía
Núñez Flores, Ruth
Ancos, Begoña de
author_role author
author2 Ojeda, Gonzalo Adrián
Sgroppo, Sonia Cecilia
Olmedilla Alonso, Begoña
Sánchez-Moreno, Concepción
Sánchez Prieto, Milagros
Giménez, Lucía
Núñez Flores, Ruth
Ancos, Begoña de
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidad Complutense de Madrid
dc.subject.none.fl_str_mv 615:54
615.31
Química analítica (Farmacia)
2301 Química Analítica
topic 615:54
615.31
Química analítica (Farmacia)
2301 Química Analítica
description This work offers a side-by-side overview of the behaviour of two liquors obtained via two fractionation processes, ionosolv and organosolv, from Eucalyptus globulus wood, and how the precipitation strategy that follows may affect the final yield, morphology, and particle size of every kind of lignin nanoparticle. For lignin nanoparticle precipitation, two bottom-up techniques and two top-down approaches were employed to determine which combination of fractionation process and synthesis treatment would provide the nanoparticles with the best characteristics. The results demonstrated the importance of the fractionation process in the final lignin nanoparticle yield, as ionosolv fractionation gave enhanced yields of more than 60% lignin in the form of nanoparticles. However, sphericity, particle sizes, and non-agglomerated structures were easily obtained from organosolv liquors, in which precipitation was carried out progressively in the absence of sonication. The use of ultrasound mostly resulted in the breakage of particles into smaller and irregular pieces. However, in the case of ionosolv liquors, homogeneous spherical nanoparticles were fused, forming agglomerates of smaller particles through the top-down strategy of complete addition of the antisolvent followed by sonication. The highest precipitation yield of nanoparticles was obtained from ionosolv liquors in which the full amount of antisolvent was added in one step to precipitate lignin, and then sonication was applied. In contrast, the lignin nanoparticles (LNPs) precipitation strategy that resulted in more spherical LNPs was the bottom-up strategy of precipitation by progressive antisolvent addition, resulting in visually observed non-aggregated spherical particles with a particle size distribution of 200 nm < dp < 500 nm, molecular weight of Mw = 14 000 g mol−1 , and thermal degradation property of T10% = 310 °C.
publishDate 2025
dc.date.none.fl_str_mv 2025
2025-01-01
2025
2025-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/20.500.14352/131573
url https://hdl.handle.net/20.500.14352/131573
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020 PID2020-113570RB-I00 BIORREFINERIA INTEGRADA DE MADERA Y HUESOS DE FRUTAS: ESCALADO, FORMULACION DE BIOPRODUCTOS Y ANALISIS TECNOECONOMICO
Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023 PID2021-124231OB-I00 EXTRACCION BIFASICA ACUOSA PARA LA RECUPERACION Y REUTILIZACION DE LIQUIDOS IONICOS AGUAS ABAJO DE LOS PROCESOS DE BIORREFINERIA ()
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution 4.0 International
http://creativecommons.org/licenses/by/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution 4.0 International
http://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv The Royal Society of Chemistry
publisher.none.fl_str_mv The Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:Docta Complutense
instname:Universidad Complutense de Madrid (UCM)
instname_str Universidad Complutense de Madrid (UCM)
reponame_str Docta Complutense
collection Docta Complutense
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,81155

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