Pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from Posidonia oceanica waste biomass
Posidonia oceanica biomass has been valorized to produce cellulosic nanocrystals with different purification degrees at lab- and pilot plant-scale. The cellulosic nanocrystals (10 % and 20 % (w/w)) were incorporated into corn starch, producing biocomposite films by melt mixing and hot-pressing at la...
| Autores: | , , , , , , , , |
|---|---|
| Formato: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2021 |
| País: | España |
| Recursos: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/250420 |
| Acesso em linha: | http://hdl.handle.net/10261/250420 |
| Access Level: | acceso abierto |
| Palavra-chave: | Cellulosic nanocrystals Extrusion Thermoforming Pilot plant Waste biomass Biopolymers |
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Pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from Posidonia oceanica waste biomassBenito González, IsaacGöksen, GüldenPérez-Bassart, ZaidaLópez-Rubio, AmparoSánchez, RafaelAlonso, José M.Gavara, RafaelGallur, MiriamMartínez Sanz, MartaCellulosic nanocrystalsExtrusionThermoformingPilot plantWaste biomassBiopolymersPosidonia oceanica biomass has been valorized to produce cellulosic nanocrystals with different purification degrees at lab- and pilot plant-scale. The cellulosic nanocrystals (10 % and 20 % (w/w)) were incorporated into corn starch, producing biocomposite films by melt mixing and hot-pressing at lab-scale. Biocomposite films showed remarkable improvements on the mechanical and water barrier performance (up to 10-fold increase in the elastic modulus and 2-fold decrease in the water permeability). Biocomposite packaging structures were also produced at pilot plant-scale by extrusion and thermoforming. Adjusting the plasticizer formulation and increasing the nanocrystals’ loading up to the maximum enabling good processability (10 % (w/w)) allowed the production of trays with enhanced water barrier and mechanical performance, which, unlike the pure starch, kept their shape upon storage. These results highlight the potential of P. oceanica nanocrystals to improve the performance of starch-based packaging structures and demonstrates the potential of the production process to be industrially applied.This work was financially supported by the Agencia Valenciana de Innovación (AVI) (INNVAL 10/19/009 project), as a result of the outcomes from the BIOCARB-4-FOOD project granted by the “Agencia Estatal de Investigación” and co-funded by the European Union’s Horizon 2020 research and innovation programme (ERA-Net SUSFOOD2).Peer reviewedElsevierGeneralitat ValencianaMinisterio de Ciencia e Innovación (España)European CommissionConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202120212021info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/250420reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Ingléshttps://doi.org/10.1016/j.fpsl.2021.100730Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2504202026-05-22T06:33:51Z |
| dc.title.none.fl_str_mv |
Pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from Posidonia oceanica waste biomass |
| title |
Pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from Posidonia oceanica waste biomass |
| spellingShingle |
Pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from Posidonia oceanica waste biomass Benito González, Isaac Cellulosic nanocrystals Extrusion Thermoforming Pilot plant Waste biomass Biopolymers |
| title_short |
Pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from Posidonia oceanica waste biomass |
| title_full |
Pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from Posidonia oceanica waste biomass |
| title_fullStr |
Pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from Posidonia oceanica waste biomass |
| title_full_unstemmed |
Pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from Posidonia oceanica waste biomass |
| title_sort |
Pilot plant scale-up of the production of optimized starch-based biocomposites loaded with cellulosic nanocrystals from Posidonia oceanica waste biomass |
| dc.creator.none.fl_str_mv |
Benito González, Isaac Göksen, Gülden Pérez-Bassart, Zaida López-Rubio, Amparo Sánchez, Rafael Alonso, José M. Gavara, Rafael Gallur, Miriam Martínez Sanz, Marta |
| author |
Benito González, Isaac |
| author_facet |
Benito González, Isaac Göksen, Gülden Pérez-Bassart, Zaida López-Rubio, Amparo Sánchez, Rafael Alonso, José M. Gavara, Rafael Gallur, Miriam Martínez Sanz, Marta |
| author_role |
author |
| author2 |
Göksen, Gülden Pérez-Bassart, Zaida López-Rubio, Amparo Sánchez, Rafael Alonso, José M. Gavara, Rafael Gallur, Miriam Martínez Sanz, Marta |
| author2_role |
author author author author author author author author |
| dc.contributor.none.fl_str_mv |
Generalitat Valenciana Ministerio de Ciencia e Innovación (España) European Commission Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72] |
| dc.subject.none.fl_str_mv |
Cellulosic nanocrystals Extrusion Thermoforming Pilot plant Waste biomass Biopolymers |
| topic |
Cellulosic nanocrystals Extrusion Thermoforming Pilot plant Waste biomass Biopolymers |
| description |
Posidonia oceanica biomass has been valorized to produce cellulosic nanocrystals with different purification degrees at lab- and pilot plant-scale. The cellulosic nanocrystals (10 % and 20 % (w/w)) were incorporated into corn starch, producing biocomposite films by melt mixing and hot-pressing at lab-scale. Biocomposite films showed remarkable improvements on the mechanical and water barrier performance (up to 10-fold increase in the elastic modulus and 2-fold decrease in the water permeability). Biocomposite packaging structures were also produced at pilot plant-scale by extrusion and thermoforming. Adjusting the plasticizer formulation and increasing the nanocrystals’ loading up to the maximum enabling good processability (10 % (w/w)) allowed the production of trays with enhanced water barrier and mechanical performance, which, unlike the pure starch, kept their shape upon storage. These results highlight the potential of P. oceanica nanocrystals to improve the performance of starch-based packaging structures and demonstrates the potential of the production process to be industrially applied. |
| publishDate |
2021 |
| dc.date.none.fl_str_mv |
2021 2021 2021 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 Postprint info:eu-repo/semantics/acceptedVersion |
| format |
article |
| status_str |
acceptedVersion |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10261/250420 |
| url |
http://hdl.handle.net/10261/250420 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
| dc.relation.none.fl_str_mv |
https://doi.org/10.1016/j.fpsl.2021.100730 Sí |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.publisher.none.fl_str_mv |
Elsevier |
| publisher.none.fl_str_mv |
Elsevier |
| dc.source.none.fl_str_mv |
reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC) |
| instname_str |
Consejo Superior de Investigaciones Científicas (CSIC) |
| reponame_str |
DIGITAL.CSIC. Repositorio Institucional del CSIC |
| collection |
DIGITAL.CSIC. Repositorio Institucional del CSIC |
| repository.name.fl_str_mv |
|
| repository.mail.fl_str_mv |
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| _version_ |
1869419193886048256 |
| score |
15,198674 |