Spectroelectrochemical studies of electrochromic diarylethene ionic Liquids

This study establishes the photoelectrochromic properties of four diarylethene ionic liquids (DAE-ILs) composed of a diarylethene dicarboxylate (DAE) moiety, as counter-anion, and different organic cations ([Cmim], [CPyr] , [N], [P]). The synthetized ILs viscous fluids maintain the photochemical and...

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Autores: Santiago Malagon, Sara|||0000-0002-1206-1455, Cruz, Hugo|||0000-0002-1047-7342, Jordão, Noemí, Giménez-Gómez, Pablo|||0000-0003-3443-802X, Zalewska, Karolina, Muñoz-Berbel, Xavier|||0000-0002-6447-5756, Santos, Andreia F.M., Hernando, Jordi|||0000-0002-1126-4138, Branco, Luís C., Guirado, Gonzalo|||0000-0003-2128-7007
Tipo de recurso: artículo
Fecha de publicación:2022
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:265729
Acceso en línea:https://ddd.uab.cat/record/265729
https://dx.doi.org/urn:doi:10.1016/j.microc.2022.107870
Access Level:acceso abierto
Palabra clave:Diarylethene ionic liquids
Spectroelectrochemistry
Ionogels
Photoelectrochemical devices
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spelling Spectroelectrochemical studies of electrochromic diarylethene ionic LiquidsFrom solution to ionogel based devicesSantiago Malagon, Sara|||0000-0002-1206-1455Cruz, Hugo|||0000-0002-1047-7342Jordão, NoemíGiménez-Gómez, Pablo|||0000-0003-3443-802XZalewska, KarolinaMuñoz-Berbel, Xavier|||0000-0002-6447-5756Santos, Andreia F.M.Hernando, Jordi|||0000-0002-1126-4138Branco, Luís C.Guirado, Gonzalo|||0000-0003-2128-7007Diarylethene ionic liquidsSpectroelectrochemistryIonogelsPhotoelectrochemical devicesThis study establishes the photoelectrochromic properties of four diarylethene ionic liquids (DAE-ILs) composed of a diarylethene dicarboxylate (DAE) moiety, as counter-anion, and different organic cations ([Cmim], [CPyr] , [N], [P]). The synthetized ILs viscous fluids maintain the photochemical and electrochemical properties of this well-known family of photoswitches, as well as the typical features of ILs (e.g., low melting point, and high thermal and electrochemical stability). Our strategy of making multi-stimuli-responsive ionic liquids by ionic exchange opens the door to easily tune the physicochemical properties of smart DAE-ILs in function of the selected cation. Finally, those DAE-ILs are used to formulate smart ionogels (IGs), a type of materials that, by showing good conductive properties and retaining the stimuli-responsive behavior of the embedded DAE molecules, allow the fabrication of photoelectrochemical devices. 22022-01-0120222022-01-01Articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/265729https://dx.doi.org/urn:doi:10.1016/j.microc.2022.107870reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaInglésengAgencia Estatal de Investigación https://doi.org/10.13039/501100011033 PID2019-106171RB-I00open accesshttp://purl.org/coar/access_right/c_abf2Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, i la comunicació pública de l'obra, sempre que no sigui amb finalitats comercials, i sempre que es reconegui l'autoria de l'obra original. No es permet la creació d'obres derivades.https://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:2657292026-06-06T12:50:31Z
dc.title.none.fl_str_mv Spectroelectrochemical studies of electrochromic diarylethene ionic Liquids
From solution to ionogel based devices
title Spectroelectrochemical studies of electrochromic diarylethene ionic Liquids
spellingShingle Spectroelectrochemical studies of electrochromic diarylethene ionic Liquids
Santiago Malagon, Sara|||0000-0002-1206-1455
Diarylethene ionic liquids
Spectroelectrochemistry
Ionogels
Photoelectrochemical devices
title_short Spectroelectrochemical studies of electrochromic diarylethene ionic Liquids
title_full Spectroelectrochemical studies of electrochromic diarylethene ionic Liquids
title_fullStr Spectroelectrochemical studies of electrochromic diarylethene ionic Liquids
title_full_unstemmed Spectroelectrochemical studies of electrochromic diarylethene ionic Liquids
title_sort Spectroelectrochemical studies of electrochromic diarylethene ionic Liquids
dc.creator.none.fl_str_mv Santiago Malagon, Sara|||0000-0002-1206-1455
Cruz, Hugo|||0000-0002-1047-7342
Jordão, Noemí
Giménez-Gómez, Pablo|||0000-0003-3443-802X
Zalewska, Karolina
Muñoz-Berbel, Xavier|||0000-0002-6447-5756
Santos, Andreia F.M.
Hernando, Jordi|||0000-0002-1126-4138
Branco, Luís C.
Guirado, Gonzalo|||0000-0003-2128-7007
author Santiago Malagon, Sara|||0000-0002-1206-1455
author_facet Santiago Malagon, Sara|||0000-0002-1206-1455
Cruz, Hugo|||0000-0002-1047-7342
Jordão, Noemí
Giménez-Gómez, Pablo|||0000-0003-3443-802X
Zalewska, Karolina
Muñoz-Berbel, Xavier|||0000-0002-6447-5756
Santos, Andreia F.M.
Hernando, Jordi|||0000-0002-1126-4138
Branco, Luís C.
Guirado, Gonzalo|||0000-0003-2128-7007
author_role author
author2 Cruz, Hugo|||0000-0002-1047-7342
Jordão, Noemí
Giménez-Gómez, Pablo|||0000-0003-3443-802X
Zalewska, Karolina
Muñoz-Berbel, Xavier|||0000-0002-6447-5756
Santos, Andreia F.M.
Hernando, Jordi|||0000-0002-1126-4138
Branco, Luís C.
Guirado, Gonzalo|||0000-0003-2128-7007
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Diarylethene ionic liquids
Spectroelectrochemistry
Ionogels
Photoelectrochemical devices
topic Diarylethene ionic liquids
Spectroelectrochemistry
Ionogels
Photoelectrochemical devices
description This study establishes the photoelectrochromic properties of four diarylethene ionic liquids (DAE-ILs) composed of a diarylethene dicarboxylate (DAE) moiety, as counter-anion, and different organic cations ([Cmim], [CPyr] , [N], [P]). The synthetized ILs viscous fluids maintain the photochemical and electrochemical properties of this well-known family of photoswitches, as well as the typical features of ILs (e.g., low melting point, and high thermal and electrochemical stability). Our strategy of making multi-stimuli-responsive ionic liquids by ionic exchange opens the door to easily tune the physicochemical properties of smart DAE-ILs in function of the selected cation. Finally, those DAE-ILs are used to formulate smart ionogels (IGs), a type of materials that, by showing good conductive properties and retaining the stimuli-responsive behavior of the embedded DAE molecules, allow the fabrication of photoelectrochemical devices.
publishDate 2022
dc.date.none.fl_str_mv 2
2022-01-01
2022
2022-01-01
dc.type.none.fl_str_mv Article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://ddd.uab.cat/record/265729
https://dx.doi.org/urn:doi:10.1016/j.microc.2022.107870
url https://ddd.uab.cat/record/265729
https://dx.doi.org/urn:doi:10.1016/j.microc.2022.107870
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación https://doi.org/10.13039/501100011033 PID2019-106171RB-I00
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Dipòsit Digital de Documents de la UAB
instname:Universitat Autònoma de Barcelona
instname_str Universitat Autònoma de Barcelona
reponame_str Dipòsit Digital de Documents de la UAB
collection Dipòsit Digital de Documents de la UAB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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