A new double-cube nitride complex containing titanium and potassium.

The reaction of the imide-nitride complex [{Ti(eta 5-C5Me5)(mu-NH)}(3)(mu(3)-N)] with potassium iodide in pyridine at room temperature affords the adduct di-mu-iodido-1:1'kappa 4 I-bis{tri-mu(3)-imido-1:2:3 kappa 3 N;1:2:4 kappa 3 N;1:3:4 kappa 3 N-mu(3)-nitrido-2:3:4 kappa 3 N-tris[2,3,4(eta 5...

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Autores: Martín Alonso, Avelino|||0000-0002-9776-9670, Mena Montoro, Miguel|||0000-0001-7456-1212, Pérez Redondo, Adrián|||0000-0002-0086-8825, Yélamos Sánchez, Carlos|||0000-0003-0425-4799
Tipo de recurso: artículo
Fecha de publicación:2011
País:España
Institución:Universidad de Alcalá (UAH)
Repositorio:e_Buah Biblioteca Digital Universidad de Alcalá
Idioma:inglés
OAI Identifier:oai:ebuah.uah.es:10017/39790
Acceso en línea:http://hdl.handle.net/10017/39790
https://dx.doi.org/10.1107/S0108270111012686
Access Level:acceso abierto
Palabra clave:Química
Chemistry
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spelling A new double-cube nitride complex containing titanium and potassium.Martín Alonso, Avelino|||0000-0002-9776-9670Mena Montoro, Miguel|||0000-0001-7456-1212Pérez Redondo, Adrián|||0000-0002-0086-8825Yélamos Sánchez, Carlos|||0000-0003-0425-4799QuímicaChemistryThe reaction of the imide-nitride complex [{Ti(eta 5-C5Me5)(mu-NH)}(3)(mu(3)-N)] with potassium iodide in pyridine at room temperature affords the adduct di-mu-iodido-1:1'kappa 4 I-bis{tri-mu(3)-imido-1:2:3 kappa 3 N;1:2:4 kappa 3 N;1:3:4 kappa 3 N-mu(3)-nitrido-2:3:4 kappa 3 N-tris[2,3,4(eta 5)-pentamethylcyclopentadienyl](pyridine-1 kappa N)-tetrahedro-potassiumtrititanium(IV)}, [K2Ti6(C10H15)(6)I2N2(NH)(6)(C5H5N)(2)] or [(C5H5N)(mu-I)K{(mu(3)-NH)(3)Ti-3(eta 5-C5Me5)(3)(mu(3)-N)}](2). The crystal structure contains two [KTi3N4] cube-type units held together by two bridging I atoms. There is a centre of inversion located in the middle of this unprecedented discrete K2I2 unit. The geometry around K is best described as distorted trigonal prismatic, with three imide groups, two bridging I atoms and one pyridine ligand.Ministerio de Educación y CienciaComisión Asesora de Investigación Científica y Técnica20112011-04-28journal articlehttp://purl.org/coar/resource_type/c_6501NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10017/39790https://dx.doi.org/10.1107/S0108270111012686reponame:e_Buah Biblioteca Digital Universidad de Alcaláinstname:Universidad de Alcalá (UAH)InglésengMinisterio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 CTQ2008-00061%2FBQU ESCAICYT Plan Nacional de I+D+i 2008-2011 CSD2006-00015 Factoría de cristalizaciónopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:ebuah.uah.es:10017/397902026-06-18T11:13:07Z
dc.title.none.fl_str_mv A new double-cube nitride complex containing titanium and potassium.
title A new double-cube nitride complex containing titanium and potassium.
spellingShingle A new double-cube nitride complex containing titanium and potassium.
Martín Alonso, Avelino|||0000-0002-9776-9670
Química
Chemistry
title_short A new double-cube nitride complex containing titanium and potassium.
title_full A new double-cube nitride complex containing titanium and potassium.
title_fullStr A new double-cube nitride complex containing titanium and potassium.
title_full_unstemmed A new double-cube nitride complex containing titanium and potassium.
title_sort A new double-cube nitride complex containing titanium and potassium.
dc.creator.none.fl_str_mv Martín Alonso, Avelino|||0000-0002-9776-9670
Mena Montoro, Miguel|||0000-0001-7456-1212
Pérez Redondo, Adrián|||0000-0002-0086-8825
Yélamos Sánchez, Carlos|||0000-0003-0425-4799
author Martín Alonso, Avelino|||0000-0002-9776-9670
author_facet Martín Alonso, Avelino|||0000-0002-9776-9670
Mena Montoro, Miguel|||0000-0001-7456-1212
Pérez Redondo, Adrián|||0000-0002-0086-8825
Yélamos Sánchez, Carlos|||0000-0003-0425-4799
author_role author
author2 Mena Montoro, Miguel|||0000-0001-7456-1212
Pérez Redondo, Adrián|||0000-0002-0086-8825
Yélamos Sánchez, Carlos|||0000-0003-0425-4799
author2_role author
author
author
dc.subject.none.fl_str_mv Química
Chemistry
topic Química
Chemistry
description The reaction of the imide-nitride complex [{Ti(eta 5-C5Me5)(mu-NH)}(3)(mu(3)-N)] with potassium iodide in pyridine at room temperature affords the adduct di-mu-iodido-1:1'kappa 4 I-bis{tri-mu(3)-imido-1:2:3 kappa 3 N;1:2:4 kappa 3 N;1:3:4 kappa 3 N-mu(3)-nitrido-2:3:4 kappa 3 N-tris[2,3,4(eta 5)-pentamethylcyclopentadienyl](pyridine-1 kappa N)-tetrahedro-potassiumtrititanium(IV)}, [K2Ti6(C10H15)(6)I2N2(NH)(6)(C5H5N)(2)] or [(C5H5N)(mu-I)K{(mu(3)-NH)(3)Ti-3(eta 5-C5Me5)(3)(mu(3)-N)}](2). The crystal structure contains two [KTi3N4] cube-type units held together by two bridging I atoms. There is a centre of inversion located in the middle of this unprecedented discrete K2I2 unit. The geometry around K is best described as distorted trigonal prismatic, with three imide groups, two bridging I atoms and one pyridine ligand.
publishDate 2011
dc.date.none.fl_str_mv 2011
2011-04-28
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
NA
http://purl.org/coar/version/c_be7fb7dd8ff6fe43
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10017/39790
https://dx.doi.org/10.1107/S0108270111012686
url http://hdl.handle.net/10017/39790
https://dx.doi.org/10.1107/S0108270111012686
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Ministerio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 CTQ2008-00061%2FBQU ES
CAICYT Plan Nacional de I+D+i 2008-2011 CSD2006-00015 Factoría de cristalización
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:e_Buah Biblioteca Digital Universidad de Alcalá
instname:Universidad de Alcalá (UAH)
instname_str Universidad de Alcalá (UAH)
reponame_str e_Buah Biblioteca Digital Universidad de Alcalá
collection e_Buah Biblioteca Digital Universidad de Alcalá
repository.name.fl_str_mv
repository.mail.fl_str_mv
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