Mercury or Silver Atoms Bridging Trinuclear Titanium Imido-Nitrido Systems

The imido - nitrido complex [{Ti(eta(5)-C5Me5)(mu-NH)}(3)(mu(3)-N)] entraps mercury(II) or silver(I) halides MXn to give cube-type adducts [XnM{(mu(3)-NH)(3)Ti-3(eta(5)-C5Me5)(3)(mu(3)-N)}] which react with alkali metal bis(trimethylsilyl) amide reagents to afford [M-2{(mu(3)-N)(n)(mu(3)-NH)(2-n)Ti-...

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Detalhes bibliográficos
Autores: Martín Alonso, Avelino|||0000-0002-9776-9670, Martínez Espada, Noelia, Mena Montoro, Miguel|||0000-0001-7456-1212, González Mosquera, Marta Elena|||0000-0003-2248-3050, Pérez Redondo, Adrián|||0000-0002-0086-8825, Yélamos Sánchez, Carlos|||0000-0003-0425-4799
Formato: artículo
Fecha de publicación:2008
País:España
Recursos:Universidad de Alcalá (UAH)
Repositorio:e_Buah Biblioteca Digital Universidad de Alcalá
Idioma:inglés
OAI Identifier:oai:ebuah.uah.es:10017/38492
Acesso em linha:http://hdl.handle.net/10017/38492
https://dx.doi.org/10.1039/B814982H, Communication
Access Level:acceso abierto
Palavra-chave:Química
Chemistry
Descrição
Resumo:The imido - nitrido complex [{Ti(eta(5)-C5Me5)(mu-NH)}(3)(mu(3)-N)] entraps mercury(II) or silver(I) halides MXn to give cube-type adducts [XnM{(mu(3)-NH)(3)Ti-3(eta(5)-C5Me5)(3)(mu(3)-N)}] which react with alkali metal bis(trimethylsilyl) amide reagents to afford [M-2{(mu(3)-N)(n)(mu(3)-NH)(2-n)Ti-3(eta(5)-C5Me5)(3)(mu-NH)(mu(3)-N)}(2)] (M = Hg, n = 2; M = Ag, n = 1) where two [Ti3N4] cores are linked by two mercury or silver atoms in a linear geometry.

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