Observation of heterogeneities in elastocaloric natural/wastes rubber composites.

The strain-induced crystallization and elastocaloric properties of various natural rubber (NR)/ground tire rubber (GTR) blends, comprising waste particles of diverse sizes and contents, were investigated. The decreasing inter-distance between particles in conjunction with their increasing content as...

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Detalles Bibliográficos
Autores: Candau, Nicolas, Vives i Santa-Eulàlia, Eduard, Fernández Renna, Ana Inés, Oguz, Oguzhan, Corvec, Guillaume, Federico, Carlos Eloy, Fernandes, João Paulo Cosas, Stoclet, Gregory, Maspoch, Maria Lluïsa
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Institución:Universidad de Barcelona
Repositorio:Dipòsit Digital de la UB
OAI Identifier:oai:diposit.ub.edu:2445/221714
Acceso en línea:https://hdl.handle.net/2445/221714
Access Level:acceso abierto
Palabra clave:Elasticitat
Cristal·lització
Cautxú
Elasticity
Crystallization
Rubber
Descripción
Sumario:The strain-induced crystallization and elastocaloric properties of various natural rubber (NR)/ground tire rubber (GTR) blends, comprising waste particles of diverse sizes and contents, were investigated. The decreasing inter-distance between particles in conjunction with their increasing content as studied by micro-computed tomography (μCT) as well as the inter-melling between GTR and NR matrix were observed. It resulted in a strain localization in the NR matrix at the GTR and NR interface at the origin of mechanical reinforcement upon tensile deformation. In addition, GTR particles were found to show a nucleating ability on strain-induced crystallization (SIC) and elastocaloric properties independently of the particle size. The strain localization was found to relate to a localization of the temperature field, suggesting localization of the elastocaloric effect in NR/GTR blends. The evidence of such heterogeneities would be of interest for the proper design of elastocaloric waste-based rubber composites for heating/cooling applications.