Observation of heterogeneities in elastocaloric natural/wastes rubber composites

The strain-induced crystallization and elastocaloric properties of various natural rubber (NR)/ground tire rubber (GTR) blends, comprising waste particles of diverse sizes and contents, were investigated. The decreasing inter-distance between particles in conjunction with their increasing content as...

Descripción completa

Detalles Bibliográficos
Autores: Candau, Nicolas|||0000-0002-1559-8696, Vives Santa-Eulàlia, Eduard, Fernández Renna, Ana Inés, Oguz, Oguzhan, Corvec, Guillaume, Federico, Carlos Eloy, Cosas Fernandes, João Paulo, Stoclet, Grégory, Maspoch Rulduà, M. Lluïsa|||0000-0002-4813-6412
Tipo de recurso: artículo
Fecha de publicación:2022
País:España
Institución:Universitat Politècnica de Catalunya (UPC)
Repositorio:UPCommons. Portal del coneixement obert de la UPC
Idioma:inglés
OAI Identifier:oai:upcommons.upc.edu:2117/384850
Acceso en línea:https://hdl.handle.net/2117/384850
https://dx.doi.org/10.3144/expresspolymlett.2022.96
Access Level:acceso abierto
Palabra clave:Rubber -- Recycling
Rubber
Recycling
Material testing
Elastocaloric properties
Materials for energy
Cautxú -- Reciclatge
Àrees temàtiques de la UPC::Enginyeria dels materials
Descripción
Sumario:The strain-induced crystallization and elastocaloric properties of various natural rubber (NR)/ground tire rubber (GTR) blends, comprising waste particles of diverse sizes and contents, were investigated. The decreasing inter-distance between particles in conjunction with their increasing content as studied by micro-computed tomography (µCT) as well as the inter-melling between GTR and NR matrix were observed. It resulted in a strain localization in the NR matrix at the GTR and NR interface at the origin of mechanical reinforcement upon tensile deformation. In addition, GTR particles were found to show a nucleating ability on strain-induced crystallization (SIC) and elastocaloric properties independently of the particle size. The strain localization was found to relate to a localization of the temperature field, suggesting localization of the elastocaloric effect in NR/GTR blends. The evidence of such heterogeneities would be of interest for the proper design of elastocaloric waste-based rubber composites for heating/cooling applications.