Removable biobased waterborne Pressure-Sensitive Adhesives containing mixtures of isosorbide methacrylate monomers

Growing environmental concerns are enforcing sustainable recycling processes for glass substrates, especially bottles, where a fast cleaning and minimization of the use of solvents is desired. In this process, labels and adhesives are mostly removed by the addition of harsh reagents, alkaline soluti...

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Detalles Bibliográficos
Autores: Badía Rodrigo, Adrián, Agirre, Amaia, Barandiaran Sarasola, María Jesús, Leiza Recondo, José Ramón
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Universidad del País Vasco
Repositorio:Addi. Archivo Digital para la Docencia y la Investigación
OAI Identifier:oai:addi.ehu.eus:10810/65904
Acceso en línea:http://hdl.handle.net/10810/65904
Access Level:acceso abierto
Palabra clave:isosorbide methacrylate
biobased monomers
emulsion polymerization
pressure sensitive adhesives
removability in water
crosslinker
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network_acronym_str ES
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spelling Removable biobased waterborne Pressure-Sensitive Adhesives containing mixtures of isosorbide methacrylate monomersBadía Rodrigo, AdriánAgirre, AmaiaBarandiaran Sarasola, María JesúsLeiza Recondo, José Ramónisosorbide methacrylatebiobased monomersemulsion polymerizationpressure sensitive adhesivesremovability in watercrosslinkerGrowing environmental concerns are enforcing sustainable recycling processes for glass substrates, especially bottles, where a fast cleaning and minimization of the use of solvents is desired. In this process, labels and adhesives are mostly removed by the addition of harsh reagents, alkaline solutions or high temperature, increasing economic costs and harming the environment. Herein, high performance and biobased waterborne pressure-sensitive adhesives with fast removability in water have been developed using small percentages of isosorbide (derived from glucose) based methacrylate monomers. Formulations containing 2-Octyl acrylate and isobornyl methacrylate and small amounts (1 wt%) of these monomers not only yield stronger adhesive fibrils, but also promote a removability in water six times faster than that of non-isosorbide based counterparts. This waterborne isosorbide containing PSAs represent an alternative to current PSA formulations towards a more sustainable glass recycling and/or reusing processes.ACS202420242020info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10810/65904reponame:Addi. Archivo Digital para la Docencia y la Investigacióninstname:Universidad del País VascoIngléshttps://pubs.acs.org/doi/full/10.1021/acs.biomac.0c00474info:eu-repo/semantics/openAccess© 2020 American Chemical Societyoai:addi.ehu.eus:10810/659042026-06-18T09:23:17Z
dc.title.none.fl_str_mv Removable biobased waterborne Pressure-Sensitive Adhesives containing mixtures of isosorbide methacrylate monomers
title Removable biobased waterborne Pressure-Sensitive Adhesives containing mixtures of isosorbide methacrylate monomers
spellingShingle Removable biobased waterborne Pressure-Sensitive Adhesives containing mixtures of isosorbide methacrylate monomers
Badía Rodrigo, Adrián
isosorbide methacrylate
biobased monomers
emulsion polymerization
pressure sensitive adhesives
removability in water
crosslinker
title_short Removable biobased waterborne Pressure-Sensitive Adhesives containing mixtures of isosorbide methacrylate monomers
title_full Removable biobased waterborne Pressure-Sensitive Adhesives containing mixtures of isosorbide methacrylate monomers
title_fullStr Removable biobased waterborne Pressure-Sensitive Adhesives containing mixtures of isosorbide methacrylate monomers
title_full_unstemmed Removable biobased waterborne Pressure-Sensitive Adhesives containing mixtures of isosorbide methacrylate monomers
title_sort Removable biobased waterborne Pressure-Sensitive Adhesives containing mixtures of isosorbide methacrylate monomers
dc.creator.none.fl_str_mv Badía Rodrigo, Adrián
Agirre, Amaia
Barandiaran Sarasola, María Jesús
Leiza Recondo, José Ramón
author Badía Rodrigo, Adrián
author_facet Badía Rodrigo, Adrián
Agirre, Amaia
Barandiaran Sarasola, María Jesús
Leiza Recondo, José Ramón
author_role author
author2 Agirre, Amaia
Barandiaran Sarasola, María Jesús
Leiza Recondo, José Ramón
author2_role author
author
author
dc.subject.none.fl_str_mv isosorbide methacrylate
biobased monomers
emulsion polymerization
pressure sensitive adhesives
removability in water
crosslinker
topic isosorbide methacrylate
biobased monomers
emulsion polymerization
pressure sensitive adhesives
removability in water
crosslinker
description Growing environmental concerns are enforcing sustainable recycling processes for glass substrates, especially bottles, where a fast cleaning and minimization of the use of solvents is desired. In this process, labels and adhesives are mostly removed by the addition of harsh reagents, alkaline solutions or high temperature, increasing economic costs and harming the environment. Herein, high performance and biobased waterborne pressure-sensitive adhesives with fast removability in water have been developed using small percentages of isosorbide (derived from glucose) based methacrylate monomers. Formulations containing 2-Octyl acrylate and isobornyl methacrylate and small amounts (1 wt%) of these monomers not only yield stronger adhesive fibrils, but also promote a removability in water six times faster than that of non-isosorbide based counterparts. This waterborne isosorbide containing PSAs represent an alternative to current PSA formulations towards a more sustainable glass recycling and/or reusing processes.
publishDate 2020
dc.date.none.fl_str_mv 2020
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10810/65904
url http://hdl.handle.net/10810/65904
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv https://pubs.acs.org/doi/full/10.1021/acs.biomac.0c00474
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
© 2020 American Chemical Society
eu_rights_str_mv openAccess
rights_invalid_str_mv © 2020 American Chemical Society
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv ACS
publisher.none.fl_str_mv ACS
dc.source.none.fl_str_mv reponame:Addi. Archivo Digital para la Docencia y la Investigación
instname:Universidad del País Vasco
instname_str Universidad del País Vasco
reponame_str Addi. Archivo Digital para la Docencia y la Investigación
collection Addi. Archivo Digital para la Docencia y la Investigación
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300724

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