Biodiesel and FAME synthesis assisted by microwaves: homogeneous batch and flow processes
Fatty acids methyl esters (FAME) have been prepared under microwave irradiation, using homogeneous catalysis, either in batch or in a flow system. The quality of the biodiesel obtained has been confirmed by GC analysis of the isolated product. While the initial experiments have been performed in a s...
| Autores: | , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 2007 |
| País: | España |
| Institución: | Universidad de Alcalá (UAH) |
| Repositorio: | e_Buah Biblioteca Digital Universidad de Alcalá |
| Idioma: | inglés |
| OAI Identifier: | oai:ebuah.uah.es:10017/3375 |
| Acceso en línea: | http://hdl.handle.net/10017/3375 https://dx.doi.org/10.1016/j.fuel.2006.11.003 |
| Access Level: | acceso abierto |
| Palabra clave: | Biodiesel FAME Microwaves Methyl-esters Catalysts Emissions Energy & fuels Engineering, Chemical Ciencia Química orgánica Science Chemistry, organic |
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Biodiesel and FAME synthesis assisted by microwaves: homogeneous batch and flow processesHernando, J.Letón García, Pedro|||0000-0002-0384-6189Matía Martín, María de la PazNovella Robisco, José Luis|||0009-0009-8169-4182Álvarez-Builla Gómez, JulioBiodieselFAMEMicrowavesMethyl-estersCatalystsEmissionsEnergy & fuelsEngineering, ChemicalCienciaQuímica orgánicaScienceChemistry, organicFatty acids methyl esters (FAME) have been prepared under microwave irradiation, using homogeneous catalysis, either in batch or in a flow system. The quality of the biodiesel obtained has been confirmed by GC analysis of the isolated product. While the initial experiments have been performed in a small scale laboratory batch reactor, the best experiment has been straightforward converted into a stop-flow process, by the use of a microwave flow system. Compared with conventional heating methods, the process using microwaves irradiation proved to be a faster method for alcoholysis of triglycerides with methanol, leading to high yields of FAME.Elsevier20072007-01-01journal articlehttp://purl.org/coar/resource_type/c_6501NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10017/3375https://dx.doi.org/10.1016/j.fuel.2006.11.003reponame:e_Buah Biblioteca Digital Universidad de Alcaláinstname:Universidad de Alcalá (UAH)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:ebuah.uah.es:10017/33752026-06-18T11:13:07Z |
| dc.title.none.fl_str_mv |
Biodiesel and FAME synthesis assisted by microwaves: homogeneous batch and flow processes |
| title |
Biodiesel and FAME synthesis assisted by microwaves: homogeneous batch and flow processes |
| spellingShingle |
Biodiesel and FAME synthesis assisted by microwaves: homogeneous batch and flow processes Hernando, J. Biodiesel FAME Microwaves Methyl-esters Catalysts Emissions Energy & fuels Engineering, Chemical Ciencia Química orgánica Science Chemistry, organic |
| title_short |
Biodiesel and FAME synthesis assisted by microwaves: homogeneous batch and flow processes |
| title_full |
Biodiesel and FAME synthesis assisted by microwaves: homogeneous batch and flow processes |
| title_fullStr |
Biodiesel and FAME synthesis assisted by microwaves: homogeneous batch and flow processes |
| title_full_unstemmed |
Biodiesel and FAME synthesis assisted by microwaves: homogeneous batch and flow processes |
| title_sort |
Biodiesel and FAME synthesis assisted by microwaves: homogeneous batch and flow processes |
| dc.creator.none.fl_str_mv |
Hernando, J. Letón García, Pedro|||0000-0002-0384-6189 Matía Martín, María de la Paz Novella Robisco, José Luis|||0009-0009-8169-4182 Álvarez-Builla Gómez, Julio |
| author |
Hernando, J. |
| author_facet |
Hernando, J. Letón García, Pedro|||0000-0002-0384-6189 Matía Martín, María de la Paz Novella Robisco, José Luis|||0009-0009-8169-4182 Álvarez-Builla Gómez, Julio |
| author_role |
author |
| author2 |
Letón García, Pedro|||0000-0002-0384-6189 Matía Martín, María de la Paz Novella Robisco, José Luis|||0009-0009-8169-4182 Álvarez-Builla Gómez, Julio |
| author2_role |
author author author author |
| dc.subject.none.fl_str_mv |
Biodiesel FAME Microwaves Methyl-esters Catalysts Emissions Energy & fuels Engineering, Chemical Ciencia Química orgánica Science Chemistry, organic |
| topic |
Biodiesel FAME Microwaves Methyl-esters Catalysts Emissions Energy & fuels Engineering, Chemical Ciencia Química orgánica Science Chemistry, organic |
| description |
Fatty acids methyl esters (FAME) have been prepared under microwave irradiation, using homogeneous catalysis, either in batch or in a flow system. The quality of the biodiesel obtained has been confirmed by GC analysis of the isolated product. While the initial experiments have been performed in a small scale laboratory batch reactor, the best experiment has been straightforward converted into a stop-flow process, by the use of a microwave flow system. Compared with conventional heating methods, the process using microwaves irradiation proved to be a faster method for alcoholysis of triglycerides with methanol, leading to high yields of FAME. |
| publishDate |
2007 |
| dc.date.none.fl_str_mv |
2007 2007-01-01 |
| dc.type.none.fl_str_mv |
journal article http://purl.org/coar/resource_type/c_6501 NA http://purl.org/coar/version/c_be7fb7dd8ff6fe43 |
| dc.type.openaire.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10017/3375 https://dx.doi.org/10.1016/j.fuel.2006.11.003 |
| url |
http://hdl.handle.net/10017/3375 https://dx.doi.org/10.1016/j.fuel.2006.11.003 |
| dc.language.none.fl_str_mv |
Inglés eng |
| language_invalid_str_mv |
Inglés |
| language |
eng |
| dc.rights.none.fl_str_mv |
open access http://purl.org/coar/access_right/c_abf2 Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ |
| dc.rights.openaire.fl_str_mv |
info:eu-repo/semantics/openAccess |
| rights_invalid_str_mv |
open access http://purl.org/coar/access_right/c_abf2 Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/ |
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openAccess |
| dc.format.none.fl_str_mv |
application/pdf |
| dc.publisher.none.fl_str_mv |
Elsevier |
| publisher.none.fl_str_mv |
Elsevier |
| dc.source.none.fl_str_mv |
reponame:e_Buah Biblioteca Digital Universidad de Alcalá instname:Universidad de Alcalá (UAH) |
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Universidad de Alcalá (UAH) |
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e_Buah Biblioteca Digital Universidad de Alcalá |
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e_Buah Biblioteca Digital Universidad de Alcalá |
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1869418020273651712 |
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15,301603 |