Biodiesel and FAME synthesis assisted by microwaves: homogeneous batch and flow processes

Fatty acids methyl esters (FAME) have been prepared under microwave irradiation, using homogeneous catalysis, either in batch or in a flow system. The quality of the biodiesel obtained has been confirmed by GC analysis of the isolated product. While the initial experiments have been performed in a s...

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Detalles Bibliográficos
Autores: Hernando, J., Letón García, Pedro|||0000-0002-0384-6189, Matía Martín, María de la Paz, Novella Robisco, José Luis|||0009-0009-8169-4182, Álvarez-Builla Gómez, Julio
Tipo de recurso: artículo
Fecha de publicación:2007
País:España
Institución:Universidad de Alcalá (UAH)
Repositorio:e_Buah Biblioteca Digital Universidad de Alcalá
Idioma:inglés
OAI Identifier:oai:ebuah.uah.es:10017/3375
Acceso en línea:http://hdl.handle.net/10017/3375
https://dx.doi.org/10.1016/j.fuel.2006.11.003
Access Level:acceso abierto
Palabra clave:Biodiesel
FAME
Microwaves
Methyl-esters
Catalysts
Emissions
Energy & fuels
Engineering, Chemical
Ciencia
Química orgánica
Science
Chemistry, organic
Descripción
Sumario:Fatty acids methyl esters (FAME) have been prepared under microwave irradiation, using homogeneous catalysis, either in batch or in a flow system. The quality of the biodiesel obtained has been confirmed by GC analysis of the isolated product. While the initial experiments have been performed in a small scale laboratory batch reactor, the best experiment has been straightforward converted into a stop-flow process, by the use of a microwave flow system. Compared with conventional heating methods, the process using microwaves irradiation proved to be a faster method for alcoholysis of triglycerides with methanol, leading to high yields of FAME.