Optically active endocyclic cyclopalladated derivatives of N-benzylidene-(R)-(1)-phenylethylamines

The action of Pd(AcO)2 on imines derived from (R)-1-phenylethylamine, R1CR:NCHMePh, [R1 = 4-ClC6H4, R = H (1); R1 = 3,5-F2C6H3, R = H (2) and R1 = C6H5, R = Me (3)] and subsequent treatment with LiBr gives the corresponding optically active cyclopalladated dimers I. In all cases the endocyclic deriv...

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Detalles Bibliográficos
Autores: Albert Mach, Joan, Granell Sanvicente, Jaime Ramón, Mínguez, Jorge
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:1996
País:España
Institución:Universidad de Barcelona
Repositorio:Dipòsit Digital de la UB
OAI Identifier:oai:diposit.ub.edu:2445/173121
Acceso en línea:https://hdl.handle.net/2445/173121
Access Level:acceso abierto
Palabra clave:Pal·ladi (Element químic)
Imines
Quiralitat
Propietats òptiques
Palladium
Chirality
Optical properties
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spelling Optically active endocyclic cyclopalladated derivatives of N-benzylidene-(R)-(1)-phenylethylaminesAlbert Mach, JoanGranell Sanvicente, Jaime RamónMínguez, JorgePal·ladi (Element químic)IminesQuiralitatPropietats òptiquesPalladiumIminesChiralityOptical propertiesThe action of Pd(AcO)2 on imines derived from (R)-1-phenylethylamine, R1CR:NCHMePh, [R1 = 4-ClC6H4, R = H (1); R1 = 3,5-F2C6H3, R = H (2) and R1 = C6H5, R = Me (3)] and subsequent treatment with LiBr gives the corresponding optically active cyclopalladated dimers I. In all cases the endocyclic derivs. were formed selectively, even with the imine 2, which contains fluoro substituents on the C atom adjacent to the metalation position. The action of PPh3 on the bromo bridged compds. I affords mononuclear II.Real Sociedad Española de Química1996info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://hdl.handle.net/2445/173121Articles publicats en revistes (Química Inorgànica i Orgànica)reponame:Dipòsit Digital de la UBinstname:Universidad de BarcelonaInglésReproducció del document publicat a:Anales de Quimica, 1996, vol. 92, p. 396-399(c) Real Sociedad Española de Química , 1996info:eu-repo/semantics/openAccessoai:diposit.ub.edu:2445/1731212026-05-27T06:46:51Z
dc.title.none.fl_str_mv Optically active endocyclic cyclopalladated derivatives of N-benzylidene-(R)-(1)-phenylethylamines
title Optically active endocyclic cyclopalladated derivatives of N-benzylidene-(R)-(1)-phenylethylamines
spellingShingle Optically active endocyclic cyclopalladated derivatives of N-benzylidene-(R)-(1)-phenylethylamines
Albert Mach, Joan
Pal·ladi (Element químic)
Imines
Quiralitat
Propietats òptiques
Palladium
Imines
Chirality
Optical properties
title_short Optically active endocyclic cyclopalladated derivatives of N-benzylidene-(R)-(1)-phenylethylamines
title_full Optically active endocyclic cyclopalladated derivatives of N-benzylidene-(R)-(1)-phenylethylamines
title_fullStr Optically active endocyclic cyclopalladated derivatives of N-benzylidene-(R)-(1)-phenylethylamines
title_full_unstemmed Optically active endocyclic cyclopalladated derivatives of N-benzylidene-(R)-(1)-phenylethylamines
title_sort Optically active endocyclic cyclopalladated derivatives of N-benzylidene-(R)-(1)-phenylethylamines
dc.creator.none.fl_str_mv Albert Mach, Joan
Granell Sanvicente, Jaime Ramón
Mínguez, Jorge
author Albert Mach, Joan
author_facet Albert Mach, Joan
Granell Sanvicente, Jaime Ramón
Mínguez, Jorge
author_role author
author2 Granell Sanvicente, Jaime Ramón
Mínguez, Jorge
author2_role author
author
dc.subject.none.fl_str_mv Pal·ladi (Element químic)
Imines
Quiralitat
Propietats òptiques
Palladium
Imines
Chirality
Optical properties
topic Pal·ladi (Element químic)
Imines
Quiralitat
Propietats òptiques
Palladium
Imines
Chirality
Optical properties
description The action of Pd(AcO)2 on imines derived from (R)-1-phenylethylamine, R1CR:NCHMePh, [R1 = 4-ClC6H4, R = H (1); R1 = 3,5-F2C6H3, R = H (2) and R1 = C6H5, R = Me (3)] and subsequent treatment with LiBr gives the corresponding optically active cyclopalladated dimers I. In all cases the endocyclic derivs. were formed selectively, even with the imine 2, which contains fluoro substituents on the C atom adjacent to the metalation position. The action of PPh3 on the bromo bridged compds. I affords mononuclear II.
publishDate 1996
dc.date.none.fl_str_mv 1996
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/173121
url https://hdl.handle.net/2445/173121
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Reproducció del document publicat a:
Anales de Quimica, 1996, vol. 92, p. 396-399
dc.rights.none.fl_str_mv (c) Real Sociedad Española de Química , 1996
info:eu-repo/semantics/openAccess
rights_invalid_str_mv (c) Real Sociedad Española de Química , 1996
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Real Sociedad Española de Química
publisher.none.fl_str_mv Real Sociedad Española de Química
dc.source.none.fl_str_mv Articles publicats en revistes (Química Inorgànica i Orgànica)
reponame:Dipòsit Digital de la UB
instname:Universidad de Barcelona
instname_str Universidad de Barcelona
reponame_str Dipòsit Digital de la UB
collection Dipòsit Digital de la UB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300719

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