Encapsulation of a trinuclear silver(I) cluster by two imido-nitrido metalloligands [{Ti(η5-C5Me5)(μ-NH)}3(μ3-N)]

Treatment of the metalloligand [{Ti(eta(5)-C5Me5)(mu-NH)}(3)(mu(3)-N)] with silver(I) trifluoromethanesulfonate in different molar ratios gives the ionic compounds [Ag{(mu(3)-NH)(3)Ti-3(eta(5)-C5Me5)(3)(mu(3)-N)}(2)][O3SCF3] and [Ag{(mu(3)-NH)(3)Ti-3(eta(5)-C5Me5)(3)(mu(3)-N)}] [O3SCF3] or the trian...

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Detalles Bibliográficos
Autores: Martín Alonso, Avelino|||0000-0002-9776-9670, Martínez Espada, Noelia, Mena Montoro, Miguel|||0000-0001-7456-1212, Yélamos Sánchez, Carlos|||0000-0003-0425-4799
Tipo de recurso: artículo
Fecha de publicación:2007
País:España
Institución:Universidad de Alcalá (UAH)
Repositorio:e_Buah Biblioteca Digital Universidad de Alcalá
Idioma:inglés
OAI Identifier:oai:ebuah.uah.es:10017/39791
Acceso en línea:http://hdl.handle.net/10017/39791
https://dx.doi.org/10.1039/b704180b
Access Level:acceso abierto
Palabra clave:Química
Chemistry
Descripción
Sumario:Treatment of the metalloligand [{Ti(eta(5)-C5Me5)(mu-NH)}(3)(mu(3)-N)] with silver(I) trifluoromethanesulfonate in different molar ratios gives the ionic compounds [Ag{(mu(3)-NH)(3)Ti-3(eta(5)-C5Me5)(3)(mu(3)-N)}(2)][O3SCF3] and [Ag{(mu(3)-NH)(3)Ti-3(eta(5)-C5Me5)(3)(mu(3)-N)}] [O3SCF3] or the triangular silver cluster [(CF3SO2O)(3)Ag-3{(mu(3)-NH) Ti-3(3)(eta(5)-C5Me5)(3)(mu(3)-N)}(2)] in which each face is capped by a metalloligand.

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