Self-assembly of a supramolecular spin-crossover tetrahedron

This article is part of the themed collection: Recent progress and perspectives on spin transition compounds.

Detalhes bibliográficos
Autores: Nielsen, Hannah H., Vilariño, Pol, Rodríguez, Gemma, Trepard, Florian, Roubeau, Olivier, Aromí, Guillem
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:2024
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositório:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/370968
Acesso em linha:http://hdl.handle.net/10261/370968
Access Level:Acceso aberto
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spelling Self-assembly of a supramolecular spin-crossover tetrahedronNielsen, Hannah H.Vilariño, PolRodríguez, GemmaTrepard, FlorianRoubeau, OlivierAromí, GuillemThis article is part of the themed collection: Recent progress and perspectives on spin transition compounds.A new mononuclear iron(II) SCO compound featuring H-bonding donor and acceptor units has been synthesized and exploited to produce a purely supramolecular switchable [Fe4] tetrahedron. Magnetic and crystallographic measurements evidence a singular magnetic behavior for each of the four Fe(II) centers of the generated architecture and underscore the potential of this strategy to develop novel SCO materials.The authors acknowledge funding by the Spanish MCIN through PID2022-137764OB-I00 (GA and DA), TED2021-129214B-I00 (GA and DA), PID2020-118329RB-I00 (OR) and CNS2022-135816 (DA), the Generalitat de Catalunya for the ICREA Academia Prize 2023 (GA) and the Danish Ministry for Higher Education and Science (Q-MAT Lighthouse) (HHN).Peer reviewedRoyal Society of Chemistry (UK)Agencia Estatal de Investigación (España)Ministerio de Ciencia, Innovación y Universidades (España)Generalitat de CatalunyaMinistry of Higher Education and Science (Denmark)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202420242024info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10261/370968reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2022-137764OB-I00info:eu-repo/grantAgreement/AEI//TED2021-129214B-I00info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-118329RB-I00The underlying dataset has been published as supplementary material of the article in the publisher platform at DOI 10.1039/d4dt00578chttps://doi.org/10.1039/d4dt00578cSíinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3709682026-05-22T06:33:51Z
dc.title.none.fl_str_mv Self-assembly of a supramolecular spin-crossover tetrahedron
title Self-assembly of a supramolecular spin-crossover tetrahedron
spellingShingle Self-assembly of a supramolecular spin-crossover tetrahedron
Nielsen, Hannah H.
title_short Self-assembly of a supramolecular spin-crossover tetrahedron
title_full Self-assembly of a supramolecular spin-crossover tetrahedron
title_fullStr Self-assembly of a supramolecular spin-crossover tetrahedron
title_full_unstemmed Self-assembly of a supramolecular spin-crossover tetrahedron
title_sort Self-assembly of a supramolecular spin-crossover tetrahedron
dc.creator.none.fl_str_mv Nielsen, Hannah H.
Vilariño, Pol
Rodríguez, Gemma
Trepard, Florian
Roubeau, Olivier
Aromí, Guillem
author Nielsen, Hannah H.
author_facet Nielsen, Hannah H.
Vilariño, Pol
Rodríguez, Gemma
Trepard, Florian
Roubeau, Olivier
Aromí, Guillem
author_role author
author2 Vilariño, Pol
Rodríguez, Gemma
Trepard, Florian
Roubeau, Olivier
Aromí, Guillem
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Agencia Estatal de Investigación (España)
Ministerio de Ciencia, Innovación y Universidades (España)
Generalitat de Catalunya
Ministry of Higher Education and Science (Denmark)
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
description This article is part of the themed collection: Recent progress and perspectives on spin transition compounds.
publishDate 2024
dc.date.none.fl_str_mv 2024
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
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status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/370968
url http://hdl.handle.net/10261/370968
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
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info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2022-137764OB-I00
info:eu-repo/grantAgreement/AEI//TED2021-129214B-I00
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-118329RB-I00
The underlying dataset has been published as supplementary material of the article in the publisher platform at DOI 10.1039/d4dt00578c
https://doi.org/10.1039/d4dt00578c

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dc.publisher.none.fl_str_mv Royal Society of Chemistry (UK)
publisher.none.fl_str_mv Royal Society of Chemistry (UK)
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