A Generalized Model to Predict the Liquid-Liquid Equilibrium in the Systems Furfural+Lubricating Oils

In the lubricating oil manufacturing process, the aromatic content of vacuum distillates is reduced by solvent extraction, frequently with furfural. These mixtures present very complex composition which makes difficult the description of the liquid-liquid equilibrium involved. In previous studies, t...

Descripción completa

Detalles Bibliográficos
Autores: Coto, Baudilio, van Grieken, Rafael, Peña, José L., Espada, Juan J.
Tipo de recurso: artículo
Fecha de publicación:2006
País:España
Institución:Universidad Rey Juan Carlos
Repositorio:BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
OAI Identifier:oai:burjcdigital.urjc.es:10115/3645
Acceso en línea:http://hdl.handle.net/10115/3645
Access Level:acceso abierto
Palabra clave:Combustibles Fósiles
23 Química
id ES_b9cb9cfbbb4cf166428594df9f5cd38b
oai_identifier_str oai:burjcdigital.urjc.es:10115/3645
network_acronym_str ES
network_name_str España
repository_id_str
spelling A Generalized Model to Predict the Liquid-Liquid Equilibrium in the Systems Furfural+Lubricating OilsCoto, Baudiliovan Grieken, RafaelPeña, José L.Espada, Juan J.Combustibles Fósiles23 QuímicaIn the lubricating oil manufacturing process, the aromatic content of vacuum distillates is reduced by solvent extraction, frequently with furfural. These mixtures present very complex composition which makes difficult the description of the liquid-liquid equilibrium involved. In previous studies, the possibility to describe such equilibrium by using a reduced number of pseudo-components and the NRTL model has been stated. In this work, a generalized model to describe the liquid-liquid equilibrium in the systems furfural+lubricating oils is presented. The generalized model is based on a correlation of pseudo-component properties (specific gravity, density, refractive index and sulfur content) and NRTL parameters with the oil average boiling temperature which has been developed from the model description for SPD and HND mixtures. This method allows set up a suitable thermodynamic model for any lubricant oil cut by using as experimental information only the average boiling point and three physical properties (density, refractive index and sulfur content) of the distillate used as feed. The accuracy of the model was checked by simulating single-stage extractions carried out with different lube oil cuts within the range SPD-HND in different experimental conditions. Calculated and experimental yields, furfural content and physical properties of the raffinates and extracts were compared and a good agreement was obtained.Tecnología Química y EnergéticaELSEVIER201020102006info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10115/3645reponame:BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlosinstname:Universidad Rey Juan CarlosInglésAtribución-NoComercial-SinDerivadas 3.0 Españahttp://creativecommons.org/licenses/by-nc-nd/3.0/es/info:eu-repo/semantics/openAccessoai:burjcdigital.urjc.es:10115/36452026-06-24T12:48:17Z
dc.title.none.fl_str_mv A Generalized Model to Predict the Liquid-Liquid Equilibrium in the Systems Furfural+Lubricating Oils
title A Generalized Model to Predict the Liquid-Liquid Equilibrium in the Systems Furfural+Lubricating Oils
spellingShingle A Generalized Model to Predict the Liquid-Liquid Equilibrium in the Systems Furfural+Lubricating Oils
Coto, Baudilio
Combustibles Fósiles
23 Química
title_short A Generalized Model to Predict the Liquid-Liquid Equilibrium in the Systems Furfural+Lubricating Oils
title_full A Generalized Model to Predict the Liquid-Liquid Equilibrium in the Systems Furfural+Lubricating Oils
title_fullStr A Generalized Model to Predict the Liquid-Liquid Equilibrium in the Systems Furfural+Lubricating Oils
title_full_unstemmed A Generalized Model to Predict the Liquid-Liquid Equilibrium in the Systems Furfural+Lubricating Oils
title_sort A Generalized Model to Predict the Liquid-Liquid Equilibrium in the Systems Furfural+Lubricating Oils
dc.creator.none.fl_str_mv Coto, Baudilio
van Grieken, Rafael
Peña, José L.
Espada, Juan J.
author Coto, Baudilio
author_facet Coto, Baudilio
van Grieken, Rafael
Peña, José L.
Espada, Juan J.
author_role author
author2 van Grieken, Rafael
Peña, José L.
Espada, Juan J.
author2_role author
author
author
dc.subject.none.fl_str_mv Combustibles Fósiles
23 Química
topic Combustibles Fósiles
23 Química
description In the lubricating oil manufacturing process, the aromatic content of vacuum distillates is reduced by solvent extraction, frequently with furfural. These mixtures present very complex composition which makes difficult the description of the liquid-liquid equilibrium involved. In previous studies, the possibility to describe such equilibrium by using a reduced number of pseudo-components and the NRTL model has been stated. In this work, a generalized model to describe the liquid-liquid equilibrium in the systems furfural+lubricating oils is presented. The generalized model is based on a correlation of pseudo-component properties (specific gravity, density, refractive index and sulfur content) and NRTL parameters with the oil average boiling temperature which has been developed from the model description for SPD and HND mixtures. This method allows set up a suitable thermodynamic model for any lubricant oil cut by using as experimental information only the average boiling point and three physical properties (density, refractive index and sulfur content) of the distillate used as feed. The accuracy of the model was checked by simulating single-stage extractions carried out with different lube oil cuts within the range SPD-HND in different experimental conditions. Calculated and experimental yields, furfural content and physical properties of the raffinates and extracts were compared and a good agreement was obtained.
publishDate 2006
dc.date.none.fl_str_mv 2006
2010
2010
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10115/3645
url http://hdl.handle.net/10115/3645
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.rights.none.fl_str_mv Atribución-NoComercial-SinDerivadas 3.0 España
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Atribución-NoComercial-SinDerivadas 3.0 España
http://creativecommons.org/licenses/by-nc-nd/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv ELSEVIER
publisher.none.fl_str_mv ELSEVIER
dc.source.none.fl_str_mv reponame:BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
instname:Universidad Rey Juan Carlos
instname_str Universidad Rey Juan Carlos
reponame_str BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
collection BURJC-Digital. Repositorio Institucional de la Universidad Rey Juan Carlos
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869417803068473344
score 15,812429

Similares en LA Referencia