Cross- Coupling in flow using supported catalysts: Mild and clean Suzuki-Miyaura coupling in a single pass

A mild, clean, practical, sustainable and high yielding procedure for Suzuki–Miyaura crosscoupling in a single pass using a silica-supported palladium catalyst is described. The catalyst can be used in more than 30 reactions and for more than 8 h of continuous processing without a decrease in reacti...

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Detalles Bibliográficos
Autores: M. Muñoz, Juan de, Alcázar, Jesús, Hoz Ayuso, Antonio de la, Díaz Ortiz, Ángel
Tipo de recurso: artículo
Fecha de publicación:2012
País:España
Institución:Universidad de Castilla-La Mancha
Repositorio:RUIdeRA. Repositorio Institucional de la UCLM
OAI Identifier:oai:ruidera.uclm.es:10578/38740
Acceso en línea:https://hdl.handle.net/10578/38740
Access Level:acceso abierto
Palabra clave:C-C bond formation
cross-coupling
flow chemistry
solid-supported catalyst
Suzuki– Miyaura reaction
Descripción
Sumario:A mild, clean, practical, sustainable and high yielding procedure for Suzuki–Miyaura crosscoupling in a single pass using a silica-supported palladium catalyst is described. The catalyst can be used in more than 30 reactions and for more than 8 h of continuous processing without a decrease in reactivity due to the low leaching observed. Different halides/pseudo-halides and organoboron compounds can be used without modifying the standard procedure.