Ionic circuitry with nanofluidic diodes

[EN] Ionic circuits composed of nanopores functionalized with polyelectrolyte chains can operate in aqueous solutions, thus allowing the control of electrical signals and information processing in physiological environments. We demonstrate experimentally and theoretically that different orientations...

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Detalles Bibliográficos
Autores: Ali, Mubarak, Nasir, Saima, Cervera, Javier, Mafe, Salvador, Ensinger, Wolfgang, Ramirez Hoyos, Patricio|||0000-0002-0067-4887
Tipo de recurso: artículo
Fecha de publicación:2019
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/214014
Acceso en línea:https://riunet.upv.es/handle/10251/214014
Access Level:acceso abierto
Palabra clave:Ionic circuits
Nanopores
Polyelectrolyte chains
Nanofluidic diodes
FISICA APLICADA
Descripción
Sumario:[EN] Ionic circuits composed of nanopores functionalized with polyelectrolyte chains can operate in aqueous solutions, thus allowing the control of electrical signals and information processing in physiological environments. We demonstrate experimentally and theoretically that different orientations of single-pore membranes with the same and opposite surface charges can operate reliably in series, parallel, and mixed series-parallel arrangements of two, three, and four nanofluidic diodes using schemes similar to those of solid-state electronics. We consider also different experimental procedures to externally tune the fixed charges of the molecular chains functionalized on the pore surface, showing that single-pore membranes can be used efficiently in ionic circuitry with distinct ionic environments.