Precursors of the RNA-world in space: Detection of ($Z$)-1,2-ethenediol in the interstellar medium, a key intermediate in sugar formation

We present the first detection of ($Z$)-1,2-ethenediol, (CHOH)$_2$, the enol form of glycolaldehyde, in the interstellar medium towards the G+0.693-0.027 molecular cloud located in the Galactic Center. We have derived a column density of (1.8$\pm$0.1)$\times$10$^{13}$ cm$^{-2}$, which translates int...

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Detalles Bibliográficos
Autores: Víctor M. Rivilla, Laura Colzi, Izaskun Jiménez-Serra, Jesús Martín-Pintado, Andrés Megías, Mattia Melosso, Luca Bizzocchi, Álvaro López-Gallifa, Antonio Martínez-Henares, Sarah Massalkhi, Belén Tercero, Pablo de Vicente, Jean-Claude Guillemin, Juan García de la Concepción, Fernando Rico-Villas, Shaoshan Zeng, Sergio Martín, Miguel A. Requena-Torres, Francesca Tonolo, Silvia Alessandrini, Luca Dore, Vincenzo Barone, Cristina Puzzarini
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/415425
Acceso en línea:http://hdl.handle.net/10261/415425
http://arxiv.org/abs/2203.14728v2
Access Level:acceso abierto
Palabra clave:Physics - Chemical Physics
astro-ph.GA
astro-ph.EP
Descripción
Sumario:We present the first detection of ($Z$)-1,2-ethenediol, (CHOH)$_2$, the enol form of glycolaldehyde, in the interstellar medium towards the G+0.693-0.027 molecular cloud located in the Galactic Center. We have derived a column density of (1.8$\pm$0.1)$\times$10$^{13}$ cm$^{-2}$, which translates into a molecular abundance with respect to molecular hydrogen of 1.3$\times$10$^{-10}$. The abundance ratio between glycolaldehyde and ($Z$)-1,2-ethenediol is $\sim$5.2. We discuss several viable formation routes through chemical reactions from precursors such as HCO, H$_2$CO, CHOH or CH$_2$CHOH. We also propose that this species might be an important precursor in the formation of glyceraldehyde (HOCH$_2$CHOHCHO) in the interstellar medium through combination with the hydroxymethylene (CHOH) radical.