Discovery in space of ethanolamine, the simplest phospholipid head group

Cell membranes are a key element of life because they keep the genetic material and metabolic machinery together. All present cell membranes are made of phospholipids, yet the nature of the first membranes and the origin of phospholipids are still under debate. We report here the presence of ethanol...

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Detalles Bibliográficos
Autores: Rivilla, Víctor M, Jiménez-Serra, Izaskun, Martín-Pintado, Jesús, Briones, Carlos, Rodríguez-Almeida, Lucas F, Rico-Villas, Fernando, Tercero, Belén, Zeng, Shaoshan, Colzi, Laura, de Vicente, Pablo, Carro Martín, Sergio, Requena-Torres, Miguel A
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2021
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/415409
Acceso en línea:http://hdl.handle.net/10261/415409
http://arxiv.org/abs/2105.11141v1
Access Level:acceso abierto
Palabra clave:astro-ph.SR
astrochemistry
cell membranes
ethanolamine
molecular clouds
prebiotic chemistry
astro-ph.GA
astro-ph.EP
Descripción
Sumario:Cell membranes are a key element of life because they keep the genetic material and metabolic machinery together. All present cell membranes are made of phospholipids, yet the nature of the first membranes and the origin of phospholipids are still under debate. We report here the presence of ethanolamine in space, [Formula: see text]OH, which forms the hydrophilic head of the simplest and second-most-abundant phospholipid in membranes. The molecular column density of ethanolamine in interstellar space is N = (1.51[Formula: see text]0.07)[Formula: see text], implying a molecular abundance with respect to [Formula: see text] of [Formula: see text] Previous studies reported its presence in meteoritic material, but they suggested that it is synthesized in the meteorite itself by decomposition of amino acids. However, we find that the proportion of the molecule with respect to water in the interstellar medium is similar to the one found in the meteorite ([Formula: see text]). These results indicate that ethanolamine forms efficiently in space and, if delivered onto early Earth, could have contributed to the assembling and early evolution of primitive membranes.