Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane

The treatment of [{Ti(eta(5)-C5Me5)}(4)(mu(3)-N)(4)] with NH3BH3 leads to the paramagnetic imidonitrido complex [{Ti(eta(5)-C5Me5)}(4)(mu(3)-N)(3)(mu(3)-NH)], which can also be obtained by stepwise proton and electron transfer with HOTf and [K(C5Me5)].

Detalles Bibliográficos
Autores: Caballo González, Jorge, González Moreiras, Mariano, Greño Ocariz, Maider, Mena Montoro, Miguel|||0000-0001-7456-1212, Pérez Redondo, Adrián|||0000-0002-0086-8825, Yélamos Sánchez, Carlos|||0000-0003-0425-4799
Tipo de recurso: artículo
Fecha de publicación:2014
País:España
Institución:Universidad de Alcalá (UAH)
Repositorio:e_Buah Biblioteca Digital Universidad de Alcalá
Idioma:inglés
OAI Identifier:oai:ebuah.uah.es:10017/38432
Acceso en línea:http://hdl.handle.net/10017/38432
https://dx.doi.org/10.1021/ic5015972
Access Level:acceso abierto
Palabra clave:Química
Chemistry
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spelling Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia BoraneCaballo González, JorgeGonzález Moreiras, MarianoGreño Ocariz, MaiderMena Montoro, Miguel|||0000-0001-7456-1212Pérez Redondo, Adrián|||0000-0002-0086-8825Yélamos Sánchez, Carlos|||0000-0003-0425-4799QuímicaChemistryThe treatment of [{Ti(eta(5)-C5Me5)}(4)(mu(3)-N)(4)] with NH3BH3 leads to the paramagnetic imidonitrido complex [{Ti(eta(5)-C5Me5)}(4)(mu(3)-N)(3)(mu(3)-NH)], which can also be obtained by stepwise proton and electron transfer with HOTf and [K(C5Me5)].Ministerio de Ciencia e InnovaciónUniversidad de AlcaláComisión Asesora de Investigación Científica y Técnica20142014-09-02journal articlehttp://purl.org/coar/resource_type/c_6501NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10017/38432https://dx.doi.org/10.1021/ic5015972reponame:e_Buah Biblioteca Digital Universidad de Alcaláinstname:Universidad de Alcalá (UAH)InglésengMinisterio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 Not available CTQ2008-00061%2FBQU Síntesis y reactividad de nitruros y óxidos metálicos molecularesUAH Not available GC2013-002CAICYT Plan Nacional de I+D+i 2008-2011 CSD2006-00015 Factoría de cristalizaciónopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:ebuah.uah.es:10017/384322026-06-18T11:13:07Z
dc.title.none.fl_str_mv Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane
title Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane
spellingShingle Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane
Caballo González, Jorge
Química
Chemistry
title_short Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane
title_full Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane
title_fullStr Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane
title_full_unstemmed Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane
title_sort Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane
dc.creator.none.fl_str_mv Caballo González, Jorge
González Moreiras, Mariano
Greño Ocariz, Maider
Mena Montoro, Miguel|||0000-0001-7456-1212
Pérez Redondo, Adrián|||0000-0002-0086-8825
Yélamos Sánchez, Carlos|||0000-0003-0425-4799
author Caballo González, Jorge
author_facet Caballo González, Jorge
González Moreiras, Mariano
Greño Ocariz, Maider
Mena Montoro, Miguel|||0000-0001-7456-1212
Pérez Redondo, Adrián|||0000-0002-0086-8825
Yélamos Sánchez, Carlos|||0000-0003-0425-4799
author_role author
author2 González Moreiras, Mariano
Greño Ocariz, Maider
Mena Montoro, Miguel|||0000-0001-7456-1212
Pérez Redondo, Adrián|||0000-0002-0086-8825
Yélamos Sánchez, Carlos|||0000-0003-0425-4799
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Química
Chemistry
topic Química
Chemistry
description The treatment of [{Ti(eta(5)-C5Me5)}(4)(mu(3)-N)(4)] with NH3BH3 leads to the paramagnetic imidonitrido complex [{Ti(eta(5)-C5Me5)}(4)(mu(3)-N)(3)(mu(3)-NH)], which can also be obtained by stepwise proton and electron transfer with HOTf and [K(C5Me5)].
publishDate 2014
dc.date.none.fl_str_mv 2014
2014-09-02
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
NA
http://purl.org/coar/version/c_be7fb7dd8ff6fe43
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10017/38432
https://dx.doi.org/10.1021/ic5015972
url http://hdl.handle.net/10017/38432
https://dx.doi.org/10.1021/ic5015972
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Ministerio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 Not available CTQ2008-00061%2FBQU Síntesis y reactividad de nitruros y óxidos metálicos moleculares
UAH Not available GC2013-002
CAICYT Plan Nacional de I+D+i 2008-2011 CSD2006-00015 Factoría de cristalización
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:e_Buah Biblioteca Digital Universidad de Alcalá
instname:Universidad de Alcalá (UAH)
instname_str Universidad de Alcalá (UAH)
reponame_str e_Buah Biblioteca Digital Universidad de Alcalá
collection e_Buah Biblioteca Digital Universidad de Alcalá
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