Partial Hydrogenation of a Tetranuclear Titanium Nitrido Complex with Ammonia Borane

The treatment of [{Ti(eta(5)-C5Me5)}(4)(mu(3)-N)(4)] with NH3BH3 leads to the paramagnetic imidonitrido complex [{Ti(eta(5)-C5Me5)}(4)(mu(3)-N)(3)(mu(3)-NH)], which can also be obtained by stepwise proton and electron transfer with HOTf and [K(C5Me5)].

Detalles Bibliográficos
Autores: Caballo González, Jorge, González Moreiras, Mariano, Greño Ocariz, Maider, Mena Montoro, Miguel|||0000-0001-7456-1212, Pérez Redondo, Adrián|||0000-0002-0086-8825, Yélamos Sánchez, Carlos|||0000-0003-0425-4799
Tipo de recurso: artículo
Fecha de publicación:2014
País:España
Institución:Universidad de Alcalá (UAH)
Repositorio:e_Buah Biblioteca Digital Universidad de Alcalá
Idioma:inglés
OAI Identifier:oai:ebuah.uah.es:10017/38432
Acceso en línea:http://hdl.handle.net/10017/38432
https://dx.doi.org/10.1021/ic5015972
Access Level:acceso abierto
Palabra clave:Química
Chemistry
Descripción
Sumario:The treatment of [{Ti(eta(5)-C5Me5)}(4)(mu(3)-N)(4)] with NH3BH3 leads to the paramagnetic imidonitrido complex [{Ti(eta(5)-C5Me5)}(4)(mu(3)-N)(3)(mu(3)-NH)], which can also be obtained by stepwise proton and electron transfer with HOTf and [K(C5Me5)].

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