Enantioselective Synthesis of Cyclobutenes by Intermolecular [2+2] Cycloaddition with Non‐C2 Symmetric Digold Catalysts
The enantioselective intermolecular gold- (I)-catalyzed [2+2] cycloaddition of terminal alkynes and alkenes has been achieved using non-C2-chiral Josiphos digold(I) complexes as catalysts, by the formation of the monocationic complex. This new approach has been applied to the enantioselective total...
| Autores: | , , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2017 |
| País: | España |
| Institución: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2072/335516 |
| Acceso en línea: | http://hdl.handle.net/2072/335516 https://doi.org/10.1021/jacs.7b07651 |
| Access Level: | acceso abierto |
| Palabra clave: | 54 |
| Sumario: | The enantioselective intermolecular gold- (I)-catalyzed [2+2] cycloaddition of terminal alkynes and alkenes has been achieved using non-C2-chiral Josiphos digold(I) complexes as catalysts, by the formation of the monocationic complex. This new approach has been applied to the enantioselective total synthesis of rumphellaone A. |
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