Wrapping up Metal-Organic Framework Crystals with Carbon Nanotubes

[EN] The presence of tetrazine units in the organic nodes of UiO-68-TZCD controls the formation of ultrathin coatings of single-wall nanotubes that decorate the surface of the crystal. These crystal hybrids can be prepared straightforwardly in one step and are extraordinarily respectful with the pro...

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Detalles Bibliográficos
Autores: Lerma-Berlanga, Belén|||0000-0003-3686-8576, Albero-Sancho, Josep|||0000-0002-4841-7206, García Gómez, Hermenegildo|||0000-0002-9664-493X, Padial, Natalia M., Galbiati, Marta, Brotons-Alcázar, Isaac, Forment-Aliaga, Alicia, Ganivet, Carolina R., Marti-Gastaldo, Carlos
Tipo de recurso: artículo
Fecha de publicación:2023
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/203514
Acceso en línea:https://riunet.upv.es/handle/10251/203514
Access Level:acceso abierto
Palabra clave:Carbon nanotubes
Click chemistry
Crystal hybrids
Metal-organic frameworks
Tetrazine tags
QUIMICA ORGANICA
Descripción
Sumario:[EN] The presence of tetrazine units in the organic nodes of UiO-68-TZCD controls the formation of ultrathin coatings of single-wall nanotubes that decorate the surface of the crystal. These crystal hybrids can be prepared straightforwardly in one step and are extraordinarily respectful with the properties of the framework for combination of mesoporosity and surface areas approximate to 4.000 m(2) g(-1), with excellent stability in water, and conductivities at room temperature of 4 x 10(-2) S cm(-1) even at very low carbon weight contents (2.3 wt.%).

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