Wrapping up Metal–Organic Framework Crystals with Carbon Nanotubes

The presence of tetrazine units in the organic nodes of UiO-68-TZCD controls the formation of ultrathin coatings of single-wall nanotubes that decorate the surface of the crystal. These crystal hybrids can be prepared straightforwardly in one step and are extraordinarily respectful with the properti...

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Detalles Bibliográficos
Autores: Lerma-Berlanga, Belén, Padial, Natalia M., Galbiati, Marta, Brotons-Alcázar, Isaac, Albero, J., García Gómez, Hermenegildo, Forment-Aliaga, Alicia, Ganivet, Carolina R., Martí-Gastaldo, Carlos
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/352200
Acceso en línea:http://hdl.handle.net/10261/352200
Access Level:acceso abierto
Descripción
Sumario:The presence of tetrazine units in the organic nodes of UiO-68-TZCD controls the formation of ultrathin coatings of single-wall nanotubes that decorate the surface of the crystal. These crystal hybrids can be prepared straightforwardly in one step and are extraordinarily respectful with the properties of the framework for combination of mesoporosity and surface areas ≈4.000 m g, with excellent stability in water, and conductivities at room temperature of 4 × 10 S cm even at very low carbon weight contents (2.3 wt.%).