Corrugation in exfoliated graphene: an electron microscopy and diffraction study

Low-energy electron microscopy and microprobe diffraction are used to image and characterize corrugation in SiO(2)-supported and suspended exfoliated graphene at nanometer length scales. Diffraction line-shape analysis reveals quantitative differences in surface roughness on length scales below 20 n...

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Detalles Bibliográficos
Autores: Locatelli, Andrea, Knox, Kevin R., Cvetko, Dean, Mentes, T. O., Niño, Miguel Ángel, Wang, Shancai, Yilmaz, Mehmet B, Kim, Philip, Osgood, R. M., Morgante, Alberto
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2010
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/415328
Acceso en línea:http://hdl.handle.net/10261/415328
https://api.elsevier.com/content/abstract/scopus_id/78650090613
Access Level:acceso abierto
Palabra clave:Roughness
μ-LEED
Corrugation
Exfoliated graphene
Graphene
LEEM
Morphology
Descripción
Sumario:Low-energy electron microscopy and microprobe diffraction are used to image and characterize corrugation in SiO(2)-supported and suspended exfoliated graphene at nanometer length scales. Diffraction line-shape analysis reveals quantitative differences in surface roughness on length scales below 20 nm which depend on film thickness and interaction with the substrate. Corrugation decreases with increasing film thickness, reflecting the increased stiffness of multilayer films. Specifically, single-layer graphene shows a markedly larger short-range roughness than multilayer graphene. Due to the absence of interactions with the substrate, suspended graphene displays a smoother morphology and texture than supported graphene. A specific feature of suspended single-layer films is the dependence of corrugation on both adsorbate load and temperature, which is manifested by variations in the diffraction line shape. The effects of both intrinsic and extrinsic corrugation factors are discussed.