Structural characterization of as-grown and quasi-free standing graphene layers on SiC

We report on a comparative structural characterization of two types of high quality epitaxial graphene layers grown by CVD on 4H-SiC(0001). The layers under study are a single layer graphene on top of a buffer layer and a quasi-free-standing graphene obtained by intercalation of hydrogen underneath...

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Detalles Bibliográficos
Autores: Aceituno Bueno, Rebeca, Palacio, Irene, Munuera, C., Aballe, Lucía, Foerster, Michael, Strupinski, Wlodek, García-Hernández, Mar, Martín-Gago, José A., López, María Francisca
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2018
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/170738
Acceso en línea:http://hdl.handle.net/10261/170738
Access Level:acceso abierto
Palabra clave:Graphene
SiC
LEEM/PEEM
STM
CVD
H-intercalation
Descripción
Sumario:We report on a comparative structural characterization of two types of high quality epitaxial graphene layers grown by CVD on 4H-SiC(0001). The layers under study are a single layer graphene on top of a buffer layer and a quasi-free-standing graphene obtained by intercalation of hydrogen underneath the buffer layer. We determine the morphology and structure of both layers by different complementary in-situ and ex-situ surface techniques. We found the existence of large islands in both samples but with different size distribution. Photoemission electron microscopy (PEEM) measurements were performed to get information about the chemical environment of the different regions. The study reveals that monolayer graphene prevails in most of the surface terraces, while a bilayer and trilayer graphene presence is observed at the steps, stripes along steps and islands.