Cooperative zinc/catalytic indium system for the stereoselective sequential synthesis of (E)-1,3-dienes from carbonyl compounds
Herein we describe a cooperative zinc/indium system for the stereoselective synthesis of highly functionalized (E)-1,3-dienes through the sequential allylation/elimination reaction of aldehydes and ketones with 1,3-dichloropropene. The main advantages of this methodology are that it has a broad subs...
| Autores: | , , |
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| Tipo de documento: | artigo |
| Data de publicação: | 2021 |
| País: | España |
| Recursos: | Universidad de Oviedo (UNIOVI) |
| Repositório: | RUO. Repositorio Institucional de la Universidad de Oviedo |
| Idioma: | inglês |
| OAI Identifier: | oai:digibuo.uniovi.es:10651/57810 |
| Acesso em linha: | http://hdl.handle.net/10651/57810 https://dx.doi.org/10.1039/d0qo01388a |
| Access Level: | Acceso aberto |
| Palavra-chave: | indium zinc dienes |
| Resumo: | Herein we describe a cooperative zinc/indium system for the stereoselective synthesis of highly functionalized (E)-1,3-dienes through the sequential allylation/elimination reaction of aldehydes and ketones with 1,3-dichloropropene. The main advantages of this methodology are that it has a broad substrate scope and simple procedure, requires mild conditions and is easy to operate. |
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