An Instantaneous and Highly Selective Chromofluorogenic Chemodosimeter for Fluoride Anion Detection in Pure Water

The fast and the fluoride: A pyridine derivative functionalized with tert-butyldimethylsilyl ether has been synthesized and used as a selective chromofluorogenic fluoride sensor in water/cetyltrimethylammonium bromide solutions. The chromofluorogenic response arises from the fluoride-induced hydroly...

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Detalles Bibliográficos
Autores: EL SAYED SHIHATA NASR, SAMEH, Agostini, Alessandro, Santos Figueroa, Luis E., Martínez-Máñez, Ramón|||0000-0001-5873-9674, Sancenón Galarza, Félix|||0000-0002-5205-7135
Tipo de recurso: artículo
Fecha de publicación:2013
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/36724
Acceso en línea:https://riunet.upv.es/handle/10251/36724
Access Level:acceso abierto
Palabra clave:Chemodosimeter
Colour change
Fluoride
Hydrolysis
Silyl ether
QUIMICA INORGANICA
QUIMICA ORGANICA
Descripción
Sumario:The fast and the fluoride: A pyridine derivative functionalized with tert-butyldimethylsilyl ether has been synthesized and used as a selective chromofluorogenic fluoride sensor in water/cetyltrimethylammonium bromide solutions. The chromofluorogenic response arises from the fluoride-induced hydrolysis of the silyl ether moiety, which generates a coloured and highly emissive phenolate anion.